Merrillite

Ca9NaMg(PO4)7
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mer
IMA approved
1976
Also known as
  • Merrilliet
  • Merrillite-(Na)

Where it forms, where it's found

Geological setting

Stony meteorites.

Type locality
Alfianello meteorite
  1. Alfianello
  2. Brescia Province
  3. Lombardy
  4. Italy

45.2667°, 10.1500°

239recorded occurrences
Source · OpenStreetMap

Physical

Colour
Colorless · white
Streak
White
Tenacity
very brittle
Cleavage
Poor/Indistinct

Hexagonal cleavage at times (indistinct).

Density
3.1 g/cm³

Optical

Optical type
Uniaxial (-)

Crystallography

Crystal system
Trigonal
Space group
#86
Cell parameters
a = 10.362 Å · c = 37.106 Å
Unit cell volume
3450.34 ų
Z
6
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2815.999447.972
41.76%
20CaCalciumCalcium940.078360.702
33.62%
15PPhosphorusPhosphorus730.974216.818
20.21%
12MgMagnesiumMagnesium124.30524.305
2.27%
11NaSodiumSodium122.99022.990
2.14%
Total1072.787100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Merrilliet
  • Merrillite-(Na)

In other languages

French
Merrillite
German
Merrillit
Italian
Merrillite · Merrillite-(Na)
Portuguese
Merrillite

Classification

Strunz
10th ed.

8.AC.45

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.ACWith medium-sized and large cationsGroup
  • 8.AC.45MerrilliteSpecies
Dana
8th ed.

38.03.04.04

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.03(AB)3(XO4)2Type
  • 38.03.04Whitlockite groupGroup
  • 38.03.04.04MerrilliteSpecies

Group, growth & confusion

In the same group
3 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1883Tschermak, G. (1883) Sitzber. Akad. Wiss. Wien, Math-naturw. K1.88, Abt. 1: 347-371.
  2. 1915Merrill, G. P. (1915) On the Monticellite-Like Mineral in Meteorites, and on Oldhamite as a Meteoric Constituent. Proceedings of the National Academy of Sciences, 1 (5) 302-308 doi:10.1073/pnas.1.5.302DOI: 10.1073/pnas.1.5.302
  3. 1917Wherry, Edgar T. (1917) New minerals: Merrillite, meteoritic Calcium phosphate. American Mineralogist, 2 (9) 119
  4. 1917Merrill, G.P. (1917) On the calcium phosphate in meteoric stones. American Journal of Science: 43: 322-324.
  5. 1925Shannon, E.V., Larsen, E.S. (1925) Merrillite and chloraptite from stony meteorites. American Journal of Science: 9: 250-260.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Merrillite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/merrillite-6577},
  note      = {Accessed 2026-05-11}
}