Metamunirite

NaV5+O3
IMA status
  • Approved
IMA symbol
Mmni
Discovered
1991
Also known as
  • IMA1990-044
  • Metamuniriet

Where it forms, where it's found

Geological setting

sandstone vanadium deposit

Type locality
Burro Mine
  1. San Miguel County
  2. Colorado
  3. USA

38.0451°, -108.8896°

11recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Translucent
Colour
Colourless
Tenacity
fragile
Cleavage
Perfect

(101) and (001)

Density
2.877 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 30 – 40°
Refractive index
1.78 – 1.85
Surface relief
Very high
Principal indices
nα 1.780 · nβ 1.800 · nγ 1.85
Birefringence
Note that the calculated and illustrated birefringence is a minimum, based on n<sub>γ</sub> = 1.85; because n<sub>γ</sub> is reportedly >> 1.85, the actual observed birefringence will be higher.
Dispersion
r > v distinct
Extinction
X = c; Y = a; Z = b; positive elongation
Michel-Lévy diagramhighlighted lineδ = 0.8500
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]8500 nmhigh order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation8500 nm
Orderhigh order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 14.134(7) Å · b = 3.648(2) Å · c = 5.357(2) Å
Ratio a:b:c
1 : 0.258 : 0.379
Z
4
Morphology

Needle-like crystals, which sometimes are broadened into narrow laths. Dominant crystal habit is (101), with no clearly developed terminal faces.

Type-locality form

Clusters of radiating colourless needles up to 0.2 mm in length in cavities in sandstone.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
23VVanadiumVanadium150.94250.942
41.78%
8OOxygenOxygen315.99947.997
39.36%
11NaSodiumSodium122.99022.990
18.86%
Total121.929100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1990-044
  • Metamuniriet

In other languages

German
IMA 1990-044 · Metamunirit
Italian
Metamunirite

Classification

Strunz
10th ed.

4.HD.20

  • 4OxidesClass
  • 4.HV[5,6] VanadatesDivision
  • 4.HDInovanadatesGroup
  • 4.HD.20MetamuniriteSpecies
Dana
8th ed.

47.01.03.02

  • 47Vanadium OxysaltsClass
  • 47.01Normal Anhydrous Vanadium OxysaltsType
  • 47.01.03Munirite GroupGroup
  • 47.01.03.02MetamuniriteSpecies
CIM

21.1.1

  • 21Vanadates (and vanadates with arsenate or phosphate)Class
  • 21.1Vanadates of the alkalis and CuGroup
  • 21.1.1MetamuniriteSpecies

Literature, links & citation

Citations
  1. Emmermann, A. (2026) Metamuniriet: fluorescentie verklaard? [Metamunirite: fluorescence explained?]. Geonieuws: 51(2): 34-35.
  2. 1984Kato, K., Takayama, E. (1984) Das Entwässerungsverhalten des Natriummetavanadatdihydrats und die Kristallstruktur des β-Natriummetavanadats. Acta Crystallographica Section B Structural Science, 40 (2) 102-105 doi:10.1107/s0108768184001828DOI: 10.1107/s0108768184001828
  3. 1991Evans, Howard T. (1991) Metamunirite, a new anhydrous sodium metavanadate from San Miguel County, Colorado. Mineralogical Magazine, 55 (381) 509-513 doi:10.1180/minmag.1991.055.381.02 DOI: 10.1180/minmag.1991.055.381.02
  4. 1992Jambor, John L., Puziewicz, Jacek (1992) New Mineral Names. American Mineralogist, 77 (9-10) 1116-1121
  5. 2005(2005) Metamunirite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Metamunirite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/metamunirite-2680},
  note      = {Accessed 2026-05-11}
}