Metasideronatrite

Na2Fe3+(SO4)2(OH) · H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mnat
Discovered
1938
Also known as
  • Metasideronatriet

Where it forms, where it's found

Geological setting

Weathering product of pyrite in arid areas, also formed in seashore environments.

Type locality
Sierra Gorda
  1. Antofagasta Province
  2. Antofagasta
  3. Chile
32recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101.5 – 2.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Golden yellow · straw yellow · yellow in transmitted light.
Cleavage
Perfect

Perfect on (100) (010). Nearly perfect on (001).

Fracture
Fibrous
Density
2.68 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60° · 2V calc = 76°
Refractive index
1.543 – 1.634
Surface relief
Moderate
Principal indices
nα 1.543 · nβ 1.575 · nγ 1.634
Pleochroism
Strong

X = Colourless, Y = Pale yellow, Z = Brownish yellow.

Dispersion
strong r > v
Extinction
Parallel. X = a; Y = b; Z = c.
Michel-Lévy diagramhighlighted lineδ = 0.0910
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]910 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation910 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 7.3959(8) Å · b = 16.0979(15) Å · c = 7.1607(8) Å
Ratio a:b:c
1 : 2.177 : 0.968
Z
4
Morphology

Rare crystals are prismatic [001]. Commonly in coarse to fine crystalline aggregates.

Comment

Space group Pbnm (non-standard setting of Pnma).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
48.63%
16SSulfurSulfur232.06064.120
19.49%
26FeIronIron155.84555.845
16.98%
11NaSodiumSodium222.99045.980
13.98%
1HHydrogenHydrogen31.0083.024
0.92%
Total328.959100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Metasideronatriet

In other languages

German
Metasideronatrit
Italian
Metasideronatrite

Classification

Strunz
10th ed.

7.DF.20

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.20MetasideronatriteSpecies
Dana
8th ed.

31.08.04.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.08(AB)3(XO4)2Zq·xH2OType
  • 31.08.04— unnamed intermediate level —Group
  • 31.08.04.01MetasideronatriteSpecies
CIM

25.11.3

  • 25SulphatesClass
  • 25.11Sulphates of Fe and other metalsGroup
  • 25.11.3MetasideronatriteSpecies

Literature, links & citation

Citations
  1. 1938Bandy, Mark C. (1938) Mineralogy of three sulphate deposits of northern Chile. American Mineralogist, 23 (11) 669-760
  2. 1951Palache, Charles; Berman, Harry; Frondel, Clifford (1951) The System of Mineralogy (7th ed.) Vol. 2 - Halides, Nitrates, Borates, Carbonates, Sulfates, Phosphates, Arsenates, Tungstates, Molybdates, Etc. John Wiley and Sons.
  3. 1964Cesbron, Fabien (1964) Contribution à la Minéralogie des sulfates de fer hydratés. Bulletin de Minéralogie, 87 (2) 125-143 doi:10.3406/bulmi.1964.5721DOI: 10.3406/bulmi.1964.5721
  4. 1973Finney, Joseph J. (1973) Unit cell and X-ray-powder data for metasideronatrite. American Mineralogist, 58 (11-12) 1080-1081
  5. 1982Scordari, F., Milella, G. (1982) Metasideronatrite: a mixture of coexisting compounds. Neues Jahrbuch für Mineralogie, Monatshefte: 255–264.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Metasideronatrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/metasideronatrite-2685},
  note      = {Accessed 2026-05-11}
}