Metastudtite

UO4 · 2H2O
IMA status
  • Approved
IMA symbol
Mstu
Discovered
1983
Also known as
  • IMA1981-055
  • Metastudtiet

Where it forms, where it's found

Geological setting

Secondary uranium mineral.

Type locality
Shinkolobwe Mine
  1. Shinkolobwe
  2. Kambove Territory
  3. Haut-Katanga
  4. DR Congo

-11.0486°, 26.5508°

5recorded occurrences
Source · OpenStreetMap

Radioactivity

Physical

Colour
Pale yellow
Streak
Yellowish
Tenacity
flexible
Density
4.67 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 47° · 2V calc = 48°
Refractive index
1.64 – 1.76
Surface relief
High
Principal indices
nα 1.640 · nβ 1.658 · nγ 1.760
Pleochroism
Not Visible
Dispersion
r < v moderate
Extinction
Z = c (direction of elongation).
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.1200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1200 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1200 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#71
Cell parameters
a = 8.411(1) Å · b = 8.744(1) Å · c = 6.505(1) Å
Ratio a:b:c
1 : 1.040 : 0.773
Unit cell volume
478.39 ų
Z
2
Morphology

Fibrous, or as elongated tablets, to 3 mm; in nodules.

Type-locality form

Aggregates of flexible pale yellow fibers. Also as elongated tablets.

Comment

Data from Rodriguez et al. (2016). Previously assumed to have space group Immm. "In light of the structure determination for studtite, it is likely that the correct unit cell of metastudtite is larger than previously thought, as the repeat length of the chain of uranyl polyhedra in studtite is 8.4 Å, and is not compatible with the 4.2 Å cell dimension" (Burns & Hughes, 2003).

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
92UUraniumUranium1238.029238.029
70.41%
8OOxygenOxygen615.99995.994
28.40%
1HHydrogenHydrogen41.0084.032
1.19%
Total338.055100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1981-055
  • Metastudtiet

In other languages

German
IMA 1981-055 · Metastudtit
Italian
Metastudtite

Classification

Strunz
10th ed.

4.GA.15

  • 4OxidesClass
  • 4.GUranyl HydroxidesDivision
  • 4.GAWithout additional cationsGroup
  • 4.GA.15MetastudtiteSpecies
Dana
8th ed.

05.03.01.02

  • 05Oxides Containing Uranium or ThoriumClass
  • 05.03AXO4·xH2OType
  • 05.03.01Studtite GroupGroup
  • 05.03.01.02MetastudtiteSpecies
CIM

7.16.5

  • 7Oxides and HydroxidesClass
  • 7.16Oxides of UGroup
  • 7.16.5MetastudtiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. Sato, Taishi (l96l a) Uranium peroxide hydrates. Naturwissenschaften, 48, 668. (synthetic)
  2. Sato, Taishi (l96l b) Thermal decomposition of uranium peroxide hydrates. Naturwissenschaften, 48, 693. (synthetic)
  3. 1963Debets, P.C. (1963) X-ray diffraction data on hydrated uranium peroxide. Journal of Inorganic and Nuclear Chemistry, 25 (6) 727-730 doi:10.1016/0022-1902(63)80165-7DOI: 10.1016/0022-1902(63)80165-7
  4. 1974Walenta, Kurt (1974) On studtite and its composition. American Mineralogist, 59 (1-2) 166-171
  5. 1983Deliens, Michel, Piret, Paul (1983) Metastudtite, UO4·2H2O, a new mineral from Shinkolobwe, Shaba, Zaire. American Mineralogist, 68 (3-4) 456-458
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Metastudtite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/metastudtite-2687},
  note      = {Accessed 2026-05-11}
}