Middendorfite

K3Na2Mn5Si12(O,OH)36 · 2H2O
IMA status
  • Approved
IMA symbol
Mdd
IMA approved
2005
Also known as
  • IMA2005-028
  • Middendorfiet

Where it forms, where it's found

Geological setting

late hydrothermal mineral in a hyperperalkaline pegmatite

Type locality
Hilairitovoye pegmatite
  1. 252 m level
  2. Kirovskii apatite mine
  3. Kukisvumchorr Mt
  4. Murmansk Oblast
  5. Russia

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Dark to bright orange
Streak
yellowish
Tenacity
flexible
Cleavage
Perfect

on (001)

fracture scaly

Fracture
Sub-Conchoidal
Density
2.60 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 10° · 2V calc = 21°
Refractive index
1.534 – 1.563
Surface relief
Moderate
Principal indices
nα 1.534 · nβ 1.562 · nγ 1.563
Pleochroism
Strong

X = yellowish to colorless; Y = brown; Z = deep brown

Michel-Lévy diagramhighlighted lineδ = 0.0290
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]290 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation290 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 12.55(1) Å · b = 5.721(2) Å · c = 26.86(2) Å
Cell angles
β = 114.04(7) °
Ratio a:b:c
1 : 0.456 : 2.140
Unit cell volume
1761 ų
Z
2
Type-locality form

Coarse, rhomb-like lamellar and tabular crystals up to 0.1 x 0.2 x 0.4 mm in size, combined in worm- and fan-like aggregates up to 1 mm

Comment

Point Group: 2/m or 2; Space Group: P21/m or P21.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen7415.9991183.926
59.22%
14SiSiliconSilicon1228.085337.020
16.86%
25MnManganeseManganese554.938274.690
13.74%
19KPotassiumPotassium339.098117.294
5.87%
11NaSodiumSodium222.99045.980
2.30%
1HHydrogenHydrogen401.00840.320
2.01%
Total1999.230100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2005-028
  • Middendorfiet

In other languages

German
IMA 2005-028 · Middendorfit
Italian
middendorfite

Classification

Strunz
10th ed.

9.EJ.10

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EJUnclassified phyllosilicatesGroup
  • 9.EJ.10MiddendorfiteSpecies

Literature, links & citation

Citations
  1. 2006Pekov, I.V., Chukanov, N.V., Dubinchuk, V.T., Zadov, A.E. (2006) Middendorfite, K3Na2Mn5Si12(O,OH)36•2H2O, a new mineral from Khibiny Massif, Kola Peninsula. Proceedings of the Russian Mineralogical Society: 135(3): 42-52 (in Russian with English abstract). https://rruff.info/rruff_1.0/uploads/ZRMO135N3_42.pdf
  2. 2011(2011) Middendorfite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Middendorfite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/middendorfite-28996},
  note      = {Accessed 2026-05-11}
}