Mitscherlichite

K2CuCl4 · 2H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mits
Discovered
1925
Also known as
  • Mitscherlichiet

Where it forms, where it's found

Geological setting

Secondary product of the fumarolic activity.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Greenish-blue · colourless in transmitted light
Density
2.418 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.6148 – 1.6365
Surface relief
Moderate
Principal indices
nω 1.6365 · nε 1.6148
Pleochroism
Visible

O = sky-blue; E = grass-green.

Michel-Lévy diagramhighlighted lineδ = 0.0217
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]217 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation217 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
P42/mnm
Cell parameters
a = 7.477(13) Å · c = 7.935(19) Å
Z
2
Morphology

Crystals pyramidal (011), or short prismatic [001].

Twinning

On (011) (artificial material).

Type-locality form

Minute crystals on a small stalactite of salts.

Comment

probable, synthetic

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine435.450141.800
44.37%
19KPotassiumPotassium239.09878.196
24.47%
29CuCopperCopper163.54663.546
19.89%
8OOxygenOxygen215.99931.998
10.01%
1HHydrogenHydrogen41.0084.032
1.26%
Total319.572100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Mitscherlichiet

In other languages

French
Mitscherlichite
German
Mitscherlichit
Italian
Mitscherlichite

Classification

Strunz
10th ed.

3.CJ.15

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CJWith MX6 complexes; M = Fe, Mn, CuGroup
  • 3.CJ.15MitscherlichiteSpecies
Dana
8th ed.

11.03.02.01

  • 11Halide ComplexesClass
  • 11.03AmBX4·xH2OType
  • 11.03.02— unnamed intermediate level —Group
  • 11.03.02.01MitscherlichiteSpecies
CIM

8.2.12

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.2Halides of CuGroup
  • 8.2.12MitscherlichiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1887Wyrouboff, G. (1887) Sur la forme cristalline des chlorures doubles de cuivre et des métaux alcalins. Bulletin de la Société française de Minéralogie: 10(3): 125-131.
  2. 1925Zambonini, F., Carobbi, G. (1925) Sulla presenza, tra i prodotti dell'attuale attività del Vesuvio, del tetraclorocupriato potassico diidrato, K2CuCl4·2H2O. Annali del R. Osservatorio Vesuviano: 2: 7-9.
  3. 1927Hendricks, S.B., Dickinson, R.G. (1927) The crystal structures of ammonium, potassium and rubidium cupric chloride dihydrates. Journal of the American Chemical Society: 49(9): 2149-2162.
  4. 1929Schairer, J.F. (1929) New mineral names. American Mineralogist: 14: 387-388.
  5. 1934Chrobak, L. (1934) Quantitative Spectrometric Studies of Ammonium and of Potassium Cupric Chloride Dihydrate (NH4)2CuCl4·2H2O and K2CuCl4·2H2O. Zeitschrift für Kristallographie, Mineralogie und Petrographie, Leipzig: 88(1-6): 35-47.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mitscherlichite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mitscherlichite-2729},
  note      = {Accessed 2026-05-11}
}