Mullite

Al4+2xSi2-2xO10-x (x ≈ 0.4)
IMA status
  • Approved
  • Grandfathered
IMA symbol
Mul
Discovered
1924
Also known as
  • Keramite (of Mellor and Scott)
  • Porcelainit
  • Porcelainita

Where it forms, where it's found

Geological setting

Sillimanite buchites or fused argillaceous sediments occurring as inclusions in Tertiary intrusives.

Type locality
Seabank Villa
  1. Loch Scridain area
  2. Isle of Mull
  3. Argyll and Bute
  4. Scotland
  5. UK

56.3777°, -6.0771°

106recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789106 – 7/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Colourless · white · yellow · pink · red · gray
Cleavage
Distinct/Good

Distinct on (010)

Density
3.11 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 20 – 50° · 2V calc = 34 – 50°
Refractive index
1.642 – 1.679
Surface relief
High
Principal indices
nα 1.642 – 1.653 · nβ 1.644 – 1.655 · nγ 1.654 – 1.679
Pleochroism
Visible

X=Y= colorless Z= rose-pink

Dispersion
r > v
Michel-Lévy diagramhighlighted lineδ = 0.0190
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]190 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation190 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#59
Cell parameters
a = 7.5785(6) Å · b = 7.6817(7) Å · c = 2.8864(3) Å
Ratio a:b:c
1 : 1.014 : 0.381
Z
1
Morphology

Crystals prismatic to acicular.

Type-locality form

Minute sharp crystals embedded in glass.

Comment

On synthetic material. Structure is incommensurately modulated.

Crystal structure

Chemical composition

Impurities
  • Ti
  • Fe
  • Na
  • K

Synonyms

  • Keramite (of Mellor and Scott)
  • Porcelainit
  • Porcelainita

In other languages

French
Mullite
German
Mullit
Spanish
Mullita · Porcelainita
Italian
mullite
Japanese
マル石 · ムライト · ムル石
Chinese
莫來石
Russian
муллит

Classification

Strunz
10th ed.

9.AF.20

  • 9SilicatesClass
  • 9.ANesosilicatesDivision
  • 9.AFNesosilicates with additional anions; cations in [4], [5] and/or only [6] coordinationGroup
  • 9.AF.20MulliteSpecies
Dana
8th ed.

52.02.03.01

  • 52Nesosilicates Insular Sio4 Groups and O, Oh, F, H2oClass
  • 52.02Insular SiO4 Groups and O, OH, F, and H2O with cations in [4] and >[4] coordinationType
  • 52.02.03— unnamed intermediate level —Group
  • 52.02.03.01MulliteSpecies
CIM

15.4

  • 15Silicates of AluminumClass
  • 15.4— unnamed intermediate level —Group
  • 15.4MulliteSpecies

Literature, links & citation

Citations
  1. 1924Bowen, N.L., Greig, J.W., Zies, E.G. (1924) Mullite, a silicate of alumina. Journal of the Washington Academy of Sciences: 14: 183-191.
  2. 1924Foshag, W.F. (1924) New minerals: new species. American Mineralogist: 9: 211-212.
  3. 1957Agrell, S.O., Smith, J.V. (1957) X-ray crystallography of mullite, sillimanite and praguite. Acta Crystallographica: 10: 761-761.
  4. 1959BRINDLEY, G. W.; NAKAHIRA, M. (1959) The Kaolinite-Mullite Reaction Series: I, A Survey of Outstanding Problems. Journal of the American Ceramic Society, 42 (7). 311-314 doi:10.1111/j.1151-2916.1959.tb14314.xDOI: 10.1111/j.1151-2916.1959.tb14314.x
  5. 1960AGRELL, S. O., SMITH, J. V. (1960) Cell Dimensions, Solid Solution, Polymorphism, and Identification of Mullite and Sillimanite. Journal of the American Ceramic Society, 43 (2). 69-78 doi:10.1111/j.1151-2916.1960.tb13643.xDOI: 10.1111/j.1151-2916.1960.tb13643.x
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mullite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mullite-2806},
  note      = {Accessed 2026-05-11}
}