Munirite

NaV5+O3 · 1.9H2O
IMA status
  • Approved
IMA symbol
Mni
Discovered
1983
Also known as
  • IMA1982-038
  • Muniriet

Where it forms, where it's found

Type locality
Bhimber District
  1. Azad Jammu and Kashmir
  2. Pakistan
4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Colourless · white · tinged apple-green
Density
2.43 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 75° · 2V calc = 74°
Refractive index
1.692 – 1.8
Surface relief
High
Principal indices
nα 1.692 · nβ 1.757 · nγ 1.800
Dispersion
weak to distinct
UV response
None observed
Michel-Lévy diagramhighlighted lineδ = 0.1080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1080 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1080 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 16.72(2) Å · b = 3.636(3) Å · c = 8.015(6) Å
Cell angles
β = 111.0(1) °
Ratio a:b:c
1 : 0.217 : 0.479
Z
4
Morphology

Crystals, to 3 mm, in radiating to spherical fibrous aggregates

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen4.915.99978.395
50.20%
23VVanadiumVanadium150.94250.942
32.62%
11NaSodiumSodium122.99022.990
14.72%
1HHydrogenHydrogen3.81.0083.830
2.46%
Total156.158100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1982-038
  • Muniriet

In other languages

German
IMA 1982-038 · Munirit
Italian
Munirite

Classification

Strunz
10th ed.

4.HD.15

  • 4OxidesClass
  • 4.HV[5,6] VanadatesDivision
  • 4.HDInovanadatesGroup
  • 4.HD.15MuniriteSpecies
Dana
8th ed.

47.01.03.01

  • 47Vanadium OxysaltsClass
  • 47.01Normal Anhydrous Vanadium OxysaltsType
  • 47.01.03Munirite GroupGroup
  • 47.01.03.01MuniriteSpecies
CIM

21.1.2

  • 21Vanadates (and vanadates with arsenate or phosphate)Class
  • 21.1Vanadates of the alkalis and CuGroup
  • 21.1.2MuniriteSpecies

Literature, links & citation

Citations
  1. 1977Björnberg, A., Hedman, B. (1977) The crystal structure of NaVO3·1.89H2O. Acta Chemica Scandinavica: A31: 579-584.
  2. 1983Butt, K.A., Mahmood, K. (1983) Munirite, naturally occuring sodium vanadium oxide hydrate, a new mineral. Mineralogical Magazine: 47: 391-392.
  3. 1984Dunn, Pete J., Fleischer, Michael, Francis, Carl A., Langley, Richard H., Kissin, Stephen A., Shigley, Hames E., Vanko, David A., Zilczer, Janet A. (1984) New mineral names. American Mineralogist, 69 (7-8) 810-815
  4. 1988Evans Jr., H.T., (1988) The crystallography of munirite, NaVO3·(2-x)H2O. Mineralogical Magazine: 52: 716-717.
  5. 1989Jambor, John L., Burke, Ernst A. J. (1989) New Mineral Names. American Mineralogist, 74 (11-12) 1399-1404
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Munirite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/munirite-2810},
  note      = {Accessed 2026-05-11}
}