Mutnovskite

Pb2AsS3(I,Cl,Br)
IMA status
  • Approved
IMA symbol
Mvs
IMA approved
2004
Also known as
  • IMA2004-032
  • Mutnovskiet

Where it forms, where it's found

Geological setting

High-temperature fumarole

Type locality
Mutnovsky volcano
  1. Mutnovskoe
  2. Yelizovsky District
  3. Kamchatka Krai
  4. Russia

52.4617°, 158.1642°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
ruby · dark red to blue

in thin slivers

Streak
cherry-red to orange
Tenacity
fragile
Cleavage
None Observed
Fracture
None observed
Density
6.177 g/cm³

Optical

Pleochroism

Pleochroism could not be observed due to strong internal reflections

Optical colour
Silvery lead-grey, with an iridescent tarnish
Anisotropism
Could not be observed due to strong internal reflections
Internal reflections
Orange
Tropism
Anisotropic
Reflectance R%
(34.2,34.6) 470, (33.2,33.5) 546, (32.5,32.7) 589, (31.4,31.7) 650
Reflected-light panel
32.8 %anisotropic · dual curve
Specimen sRGB 203, 144, 81
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Could not be observed due to strong internal reflections
Reflected colour
Silvery lead-grey, with an iridescent tarnish
Internal reflections
Orange

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 11.543 Å · b = 6.6764 Å · c = 9.359 Å
Ratio a:b:c
1 : 0.578 : 0.811
Unit cell volume
721.3 ų
Z
4
Morphology

a short-prismatic morphology, sometimes tabular

Type-locality form

Microscopic short-prismatic crystals up to 100 μm across.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead2207.200414.400
50.06%
53IIodineIodine1126.904126.904
15.33%
16SSulfurSulfur332.06096.180
11.62%
35BrBromineBromine179.90479.904
9.66%
33AsArsenicArsenic174.92274.922
9.05%
17ClChlorineChlorine135.45035.450
4.28%
Total827.760100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Fe
  • Cu
  • Se
  • Bi

Synonyms

  • IMA2004-032
  • Mutnovskiet

In other languages

German
IMA 2004-032 · Mutnovskit
Italian
mutnovskite

Classification

Strunz
10th ed.

2.GC.50

  • 2Sulfides and SulfosaltsClass
  • 2.GSulfarsenites, sulfantimonites, sulfbismuthitesDivision
  • 2.GCPoly-sulfarsenitesGroup
  • 2.GC.50MutnovskiteSpecies

Literature, links & citation

Citations
  1. 2006Zelenski, Michael, Balić-Žunić, Tonči, Bindi, Luca, Garavelli, Anna, Makovicky, Emil, Pinto, Daniela, Vurro, Filippo (2006) First occurrence of iodine in natural sulfosalts: The case of mutnovskite, Pb2AsS3(I,Cl,Br), a new mineral from the Mutnovsky volcano, Kamchatka Peninsula, Russian Federation. American Mineralogist, 91 (1) 21-28 doi:10.2138/am.2006.1870 DOI: 10.2138/am.2006.1870
  2. 2008Bindi, Luca, Garavelli, Anna, Pinto, Daniela, Pratesi, Giovanni, Vurro, Filippo (2008) Ordered distribution of I and Cl in the low-temperature crystal structure of mutnovskite, Pb4As2S6ICl: An X-ray single-crystal study. Journal of Solid State Chemistry, 181. 306-312 doi:10.1016/j.jssc.2007.11.032DOI: 10.1016/j.jssc.2007.11.032
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Mutnovskite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/mutnovskite-27408},
  note      = {Accessed 2026-05-11}
}