Naalasite

NaAl(AsO3OH)2·H2O
IMA status
  • Approved
IMA symbol
Naa
IMA approved
2023
Also known as
  • Naalasiet

Where it forms, where it's found

Geological setting

Oxidation of native arsenic and other As-bearing primary phases, followed by later alteration by saline fluids derived from evaporating meteoric water under hyperarid conditions.

Type locality
Torrecillas mine
  1. Iquique
  2. Iquique Province
  3. Tarapacá
  4. Chile

-20.9767°, -70.1419°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
light to medium pink
Streak
white
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.19 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.63 – 1.66
Surface relief
Moderate
Principal indices
nω 1.630 · nε 1.660
Pleochroism
Non-pleochroic
UV response
mineral does not fluoresce in long- or short-wave ultraviolet light.
Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Trigonal
Space group
#93
Cell parameters
a = 8.4796(6) Å · c = 26.399(3) Å
Z
9
Type-locality form

Tightly intergrown aggregates and druses of equant crystals, up to 0.15 mm in diameter; associated minerals also include a lavendulan-like phase

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic274.922149.844
43.08%
8OOxygenOxygen915.999143.991
41.39%
13AlAluminiumAluminium126.98226.982
7.76%
11NaSodiumSodium122.99022.990
6.61%
1HHydrogenHydrogen41.0084.032
1.16%
Total347.839100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From Mindat formula

Synonyms

  • Naalasiet

In other languages

German
IMA 2023-027 · Naalasit

Classification

Strunz
10th ed.

8.CF

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CFWith large and medium-sized cations, RO4:H2O > 1:1Group
  • 8.CFNaalasiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2023Bosi, Ferdinando; Hatert, Frédéric; Pasero, Marco; Mills, Stuart J. (2023) Newsletter 74. Mineralogical Magazine, 87 (5). 783-787 doi:10.1180/mgm.2023.54DOI: 10.1180/mgm.2023.54
  2. 2024Kampf, Anthony R., Möhn, Gerhard, Ma, Chi, Désor, Joy (2024) Naalasite, NaAl(AsO3OH)2⋅H2O, the Al analogue of nafeasite from the Torrecillas mine, Iquique Province, Chile. Mineralogical Magazine, 88 (2) 155-161 doi:10.1180/mgm.2023.96DOI: 10.1180/mgm.2023.96
  3. 2025Kampf, Anthony R.; Möhn, Gerhard; Ma, Chi; Désor, Joy (2025) Naalasite, NaAl(AsO3OH)2·H2O, the Al analogue of nafeasite from the Torrecillas mine, Iquique Province, Chile — CORRIGENDUM. Mineralogical Magazine, 89 (4). 548 doi:10.1180/mgm.2025.10132DOI: 10.1180/mgm.2025.10132
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Naalasite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/naalasite-470837},
  note      = {Accessed 2026-05-11}
}