Nalipoite

NaLi2(PO4)
IMA status
  • Approved
IMA symbol
Nlp
Discovered
1990
IMA approved
1990
Also known as
  • IMA1990-030
  • Nalipoiet
  • Unnamed (MSH UK-63)

Where it forms, where it's found

Geological setting

Sodalite syenite xenoliths in nepheline syenite

Type locality
Poudrette quarry (De-Mix quarry
  1. Demix quarry
  2. Uni-Mix quarry
  3. Carrière Mont Saint-Hilaire
  4. MSH)
  5. Mont Saint-Hilaire
  6. La Vallée-du-Richelieu RCM
  7. Montérégie
  8. Québec
  9. Canada

45.5628°, -73.1417°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
pale yellow · white · pale blue
Streak
white
Tenacity
very brittle
Cleavage
Distinct/Good

(100), (010), (001), (110) good; distinct on probable (101).

Fracture
Irregular/Uneven
Density
2.58 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 49° · 2V calc = 41°
Refractive index
1.533 – 1.541
Surface relief
Moderate
Principal indices
nα 1.533 · nβ 1.540 · nγ 1.541
Pleochroism
Non-pleochroic
Dispersion
weak
UV response
Not fluorescent
Notes

X = a, Y = c, Z = b

Michel-Lévy diagramhighlighted lineδ = 0.0080
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]80 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation80 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 6.884(2) Å · b = 9.976(4) Å · c = 4.927(2) Å
Ratio a:b:c
1 : 1.449 : 0.716
Z
4
Morphology

anhedral to subhedral blocky grains, to 2 mm.

Type-locality form

Anhedral to subhedral blocky grains up to 2 mm in sodalite or analcime and as irregular grains (0.2 mm) in cavities in sodalite syenite xenoliths in the nepheline syenite.

Comment

Space Group: Pmnb.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
48.54%
15PPhosphorusPhosphorus130.97430.974
23.49%
11NaSodiumSodium122.99022.990
17.44%
3LiLithiumLithium26.94013.880
10.53%
Total131.840100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1990-030
  • Nalipoiet
  • Unnamed (MSH UK-63)

In other languages

German
IMA 1990-030 · Nalipoit
Italian
Nalipoite
Russian
налипоит

Classification

Strunz
10th ed.

8.AA.25

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.APhosphates, etc. without additional anions, without H2ODivision
  • 8.AAWith small cations (some also with larger ones)Group
  • 8.AA.25NalipoiteSpecies
Dana
8th ed.

38.04.10.03

  • 38Anhydrous Normal Phosphates, Arsenates, and VanadatesClass
  • 38.04AXO4Type
  • 38.04.10Lithiophosphate GroupGroup
  • 38.04.10.03NalipoiteSpecies
CIM

19.1.5

  • 19PhosphatesClass
  • 19.1Phosphates of the alkali metalsGroup
  • 19.1.5NalipoiteSpecies

Literature, links & citation

Citations
  1. 1974Barczak, V.J. (1974) Characterization of Li2NaPO4. Journal of the American Ceramic Society: 57: 407-407.
  2. 1991Chao, George Y., Ercit, T. Scott (1991) Nalipoite, sodium dilithium phosphate, a new mineral species from Mont Saint-Hilaire, Quebec. The Canadian Mineralogist, 29 (3) 565-568
  3. 1991Ercit, T. Scott (1991) The crystal structure of nalipoite. The Canadian Mineralogist, 29 (3) 569-573
  4. 1992Jambor, L., Vanko, David A. (1992) New Mineral Names. American Mineralogist, 77 (3-4) 446-452
  5. 1994Rastsvetaeva, R.K., Khomyakov, A.P. (1994) A comparative crystal-chemical study of the lithium-sodium phosphates (lithiophosphate, nalipoite, olympite, and Na3PO4). Crystallography Reports: 39: 35-41.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Nalipoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/nalipoite-2833},
  note      = {Accessed 2026-05-11}
}