Natropharmacoalumite

NaAl4(AsO4)3(OH)4 · 4H2O
IMA status
  • Approved
IMA symbol
Npal
IMA approved
2010
Also known as
  • IMA2010-009
  • Natropharmacoalumiet

Where it forms, where it's found

Geological setting

Oxidation zone of a gold mine

Type locality
María Josefa Mine
  1. Rodalquilar
  2. Níjar
  3. Almería
  4. Andalusia
  5. Spain

36.8583°, -2.0839°

8recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
colorless
Streak
white
Tenacity
brittle
Cleavage
Imperfect/Fair

imperfect cleavage on (100).

Fracture
Irregular/Uneven
Density
2.564 g/cm³

Optical

Optical type
Isotropic
Surface relief
Moderate
Principal indices
n 1.556
Internal reflections
white
UV response
none
Notes

assumed to be anomalously biaxial, anomalous birefringence is typical in members of the pharmacosiderite group

Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.556

Crystallography

Crystal system
Isometric
Space group
P-4 3m
Cell parameters
a = 7.7280(3) Å
Z
1
Type-locality form

intergrown cubic crystals

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen2015.999319.980
46.53%
33AsArsenicArsenic374.922224.766
32.68%
13AlAluminiumAluminium426.982107.928
15.69%
11NaSodiumSodium122.99022.990
3.34%
1HHydrogenHydrogen121.00812.096
1.76%
Total687.760100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2010-009
  • Natropharmacoalumiet

In other languages

German
IMA 2010-009 · Natropharmakoalumit
Spanish
natrofarmacoalumita
Italian
natropharmacoalumite

Classification

Strunz
10th ed.

8.DK.12

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DKWith large and medium-sized cations, (OH, etc.):RO4 > 1:1 and < 2:1Group
  • 8.DK.12NatropharmacoalumiteSpecies
Dana
8th ed.

42.08.1b.02

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.08(AB)5(XO4)3Zq·xH2OType
  • 42.08.1b— unnamed intermediate level —Group
  • 42.08.1b.02NatropharmacoalumiteSpecies

Group, growth & confusion

In the same group
4 members
Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 2010Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2010) New minerals and nomenclature modifications approved in 2010. CNMNC Newsletter No 3. Mineralogical Magazine, 74 (3) 577-579 doi:10.1180/s0026461x00054979 DOI: 10.1180/s0026461x00054979
  2. 2010Rumsey, M. S., Mills, S. J., Spratt, J. (2010) Natropharmacoalumite, NaAl4[(OH)4(AsO4)3].4H2O, a new mineral of the pharmacosiderite supergroup and the renaming of aluminopharmacosiderite to pharmacoalumite. Mineralogical Magazine, 74 (5) 929-936 doi:10.1180/minmag.2010.074.5.929 DOI: 10.1180/minmag.2010.074.5.929
  3. 2015(2015) Natropharmacoalumite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natropharmacoalumite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natropharmacoalumite-40144},
  note      = {Accessed 2026-05-11}
}