Natrosilite

Na2Si2O5
IMA status
  • Approved
IMA symbol
Ns
Discovered
1975
Also known as
  • IMA1974-043
  • Natrosiliet
  • β-Na2Si2O5

Where it forms, where it's found

Geological setting

Pegmatitic segregations of nepheline syenite.

Type locality
Karnasurt Mountain
  1. Lovozersky District
  2. Murmansk Oblast
  3. Russia

67.8808°, 34.6817°

4recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colourless
Streak
White
Cleavage
Perfect

(100) micaceous (perfect), (001) distinct, {01l} poor.

Density
2.48 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 49 – 64° · 2V calc = 64°
Refractive index
1.507 – 1.521
Surface relief
Moderate
Principal indices
nα 1.507 · nβ 1.517 · nγ 1.521
Dispersion
none
Extinction
Y ∧ c = -12° to 2°.
Michel-Lévy diagramhighlighted lineδ = 0.0140
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]140 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation140 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 12.30(2) Å · b = 4.88(1) Å · c = 8.27(3) Å
Cell angles
β = 104.25 °
Ratio a:b:c
1 : 0.397 : 0.672
Z
4
Twinning

Twins on (100), were noted on synthetic material by Donnay and Donnay.

Type-locality form

Pseudohexagonal thick-tabular crystals to 6 cm in size.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen515.99979.995
43.92%
14SiSiliconSilicon228.08556.170
30.84%
11NaSodiumSodium222.99045.980
25.24%
Total182.145100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • K
  • H2O

Synonyms

  • IMA1974-043
  • Natrosiliet
  • β-Na2Si2O5

In other languages

French
natrosilite
German
IMA 1974-043 · Natrosilit
Italian
Natrosilite

Classification

Strunz
10th ed.

9.EE.40

  • 9SilicatesClass
  • 9.EPhyllosilicatesDivision
  • 9.EESingle tetrahedral nets of 6-membered rings connected by octahedral nets or octahedral bandsGroup
  • 9.EE.40NatrosiliteSpecies
Dana
8th ed.

74.03.05.01

  • 74Phyllosilicates Modulated LayersClass
  • 74.03Modulated Layers with joined stripsType
  • 74.03.05Na phyllosilicatesGroup
  • 74.03.05.01NatrosiliteSpecies
CIM

14.1.1

  • 14Silicates not Containing AluminumClass
  • 14.1Silicates of the alkali metalsGroup
  • 14.1.1NatrosiliteSpecies

Literature, links & citation

Citations
  1. 1924Morey, G. W., Bowen, N. L. (1924) The Binary System Sodium Metasilicate-Silica. The Journal of Physical Chemistry, 28 (11). 1167-1179 doi:10.1021/j150245a005DOI: 10.1021/j150245a005
  2. 1930Kracek, F. C. (1930) The System Sodium Oxide-Silica. The Journal of Physical Chemistry, 34 (7). 1583-1598 doi:10.1021/j150313a018DOI: 10.1021/j150313a018
  3. 1933Tilley, C. E. (1933) The ternary system, Na2SiO3 — Na2Si2O5—NaAlSiO4. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 43 (6). 406-421 doi:10.1007/bf02951360DOI: 10.1007/bf02951360
  4. 1953Donnay, Gabrielle, Donnay, J. D. H. (1953) Crystal geometry of some alkali silicates. American Mineralogist, 38 (3-4) 163-171
  5. 1954Grund, Alfred (1954) La structure cristalline du disilicate de soude β˗Na2Si2O5. Bulletin de Minéralogie, 77 (4) 775-785 doi:10.3406/bulmi.1954.4927DOI: 10.3406/bulmi.1954.4927
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natrosilite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natrosilite-2863},
  note      = {Accessed 2026-05-11}
}