Natroxalate

Na2(C2O4)
IMA status
  • Approved
IMA symbol
Nx
Also known as
  • IMA1994-053
  • Natro-Oxalat

Where it forms, where it's found

Geological setting

Hydrothermal phase in ultra-agpaitic pegmatites and hydrothermalites.

Type locality
Alluaiv Mountain
  1. Lovozersky District
  2. Murmansk Oblast
  3. Russia

67.8645°, 34.5124°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Light yellow color with a pink or greenish tint · creamy in fine-grained aggregates
Tenacity
brittle
Cleavage
Perfect

perfect (100) and distinct (001) and (221) cleavages

Fracture
Step-Like
Density
2.32 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 72° · 2V calc = 72°
Refractive index
1.415 – 1.592
Surface relief
Moderate
Principal indices
nα 1.415 · nβ 1.524 · nγ 1.592
Dispersion
relatively strong, r > v
Notes

b = Z, c ∧ X = 20deg in obtuse angle b, optic axial plane normal to (010).

Michel-Lévy diagramhighlighted lineδ = 0.1770
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1770 nm4th order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1770 nm
Order4th order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/a
Cell parameters
a = 10.426(9) Å · b = 5.255(5) Å · c = 3.479(3) Å
Cell angles
β = 92.14(8) °
Ratio a:b:c
1 : 0.504 : 0.334
Z
2
Morphology

Prismatic, elongate [001], showing (110), (001), (010), (100), and (221)

Twinning

Some crystals are twinned on (110).

Type-locality form

Granular nodules to 1–2 cm, as veinlet-like segregations, as columnar crystals 3–5 mm long and up to 1 mm thick, and as radiating aggregates of the crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen415.99963.996
47.76%
11NaSodiumSodium222.99045.980
34.31%
6CCarbonCarbon212.01124.022
17.93%
Total133.998100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1994-053
  • Natro-Oxalat

In other languages

German
IMA 1994-053 · Natroxalat
Italian
Natroxalate · Natroxalato

Classification

Strunz
10th ed.

10.AB.60

  • 10Organic CompoundsClass
  • 10.ASalts of organic acidsDivision
  • 10.ABOxalatesGroup
  • 10.AB.60NatroxalateSpecies

Literature, links & citation

Citations
  1. 1981Reed, D. A., Olmstead, M. M. (1981) Sodium oxalate structure refinement. Acta Crystallographica Section B Structural Crystallography and Crystal Chemistry, 37 (4) 938-939 doi:10.1107/s0567740881004676DOI: 10.1107/s0567740881004676
  2. 1996Khomyakov, A. P. (1996) Natroxalate Na2C2O4 – a new mineral. Zapiski Vserossijskogo Mineralogicheskogo Obshchestva, 125 (1) 126-132
  3. 1997Mandarino, Joseph A. (1997) Abstracts of New Mineral Descriptions. The Mineralogical Record, 28 (3) 219-224
  4. 1997Jambor, John L.; Pertsev, Nikolai N.; Roberts, Andrew C. (1997) New Mineral Names. American Mineralogist, 82 (3-4). 430-433
  5. 2003Frost, Ray L., Weier, Matt L. (2003) Raman spectroscopy of natural oxalates at 298 and 77 K. Journal of Raman Spectroscopy, 34 (10). 776-785 doi:10.1002/jrs.1052DOI: 10.1002/jrs.1052
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Natroxalate — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/natroxalate-7187},
  note      = {Accessed 2026-05-11}
}