Nuffieldite

Cu1.4Pb2.4Bi2.4Sb0.2S7
IMA status
  • Approved
IMA symbol
Nuf
Discovered
1968
Also known as
  • IMA1967-003
  • Nuffieldiet

Where it forms, where it's found

Geological setting

In quartz veins in quartz diorite.

Type locality
British Columbia Molybdenum Ltd. Mine
  1. Patsy Creek
  2. Kitsault
  3. Alice Arm
  4. Skeena Mining Division
  5. British Columbia
  6. Canada

55.4223°, -129.4206°

31recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Shiny lead-gray to steel-gray on fresh surface · tarnishes to pale iridescent grayish green to reddish brown.
Streak
Dark greenish gray to black.
Tenacity
very brittle
Cleavage
Very Good

Excellent parallel to [001] and indistinct perpendicular to [001].

Fracture
Irregular/Uneven · Conchoidal
Density
7.01 g/cm³

Optical

Pleochroism
Non-pleochroic
Optical colour
light gray
Anisotropism
strong, but with no color effects
Bireflectance
weak - noticeable only in contact with other grains.
Internal reflections
none
Tropism
Anisotropic
Reflectance R%
(35.9,45.5) 400, (36.7,44.6) 420, (37.2,45.9) 440, (37.4,46.3) 460, (37.8,46.6) 480, (38.1,46.6) 500, (37.7,46.6) 520, (37.8,46.3) 540, (37.7,46.2) 560, (37.5,46.1) 580, (37.3,45.8) 600, (36.9,45.4) 620, (36.9,45.1) 640, (36.5,44.9) 660, (36.7,44.4) 680, (36.2,44.0) 700
Reflected-light panel
37.1 %anisotropic · dual curve
Specimen sRGB 217, 153, 84
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
weak - noticeable only in contact with other grains.
Anisotropism
strong, but with no color effects
Reflected colour
light gray
Internal reflections
none

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 14.61 Å · b = 21.38 Å · c = 4.03 Å
Ratio a:b:c
1 : 1.463 : 0.276
Type-locality form

Prismatic to acicular crystals, deeply striated parallel to [001]. The crystals frequently occur as bundles of parallel unterminated needles (to 3 mm) in the vugs.

Comment

Non-standard space-group setting Pbnm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
83BiBismuthBismuth2.4208.980501.552
37.52%
82PbLeadLead2.4207.200497.280
37.21%
16SSulfurSulfur732.060224.420
16.79%
29CuCopperCopper1.463.54688.964
6.66%
51SbAntimonyAntimony0.2121.76024.352
1.82%
Total1336.568100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1967-003
  • Nuffieldiet

In other languages

German
IMA 1967-003 · Nuffieldit
Italian
Nuffieldite

Classification

Strunz
10th ed.

2.JB.25g

  • 2Sulfides and SulfosaltsClass
  • 2.JSulfosalts of PbS archetypeDivision
  • 2.JBGalena derivatives, with PbGroup
  • 2.JB.25gNuffielditeSpecies
Dana
8th ed.

03.03.04.01

  • 03SulfosaltsClass
  • 03.033 <ø < 4Type
  • 03.03.04— unnamed intermediate level —Group
  • 03.03.04.01NuffielditeSpecies
CIM

5.7.10

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.7Sulpharsenites etc. of Pb and other metalsGroup
  • 5.7.10NuffielditeSpecies

Literature, links & citation

Citations
  1. Moëlo, Y., Meerschaut, A., Makovicky, E. (1997): Refinement of the crystal structure of nuffieldite, Pb2Cu1.4(Pb0.4Bi0.4Sb0.2)Bi2S7: Structural relationship and genesis of complex lead sulfosalt structures. Canadian Mineralogist 35, 1497-1508. https://rruff.geo.arizona.edu/doclib/cm/vol35/CM35_1497.pdf
  2. 1968KINGSTON, P.W. (1968): Studies of mineral sulphosalts. XXI. Nuffieldite, a new species. Canadian Mineralogist 9, 439-452.
  3. 1973Kohatsu, Iwao; Wuensch, B. J. (1973) The crystal structure of nuffieldite, Pb2Cu(Pb,Bi)Bi2S7. Zeitschrift für Kristallographie, 138 (1). 343-365 doi:10.1524/zkri.1973.138.1-4.343 DOI: 10.1524/zkri.1973.138.1-4.343
  4. 1990Maurel, C., Moëlo, Y. (1990) Synthèse de la nuffieldite dans le système Bi-Pb-Sb-Cu-S. The Canadian Mineralogist 28, 745-749.
  5. 1994Mozgova, N. N., Nenasheva, S. N., Borodaev, Y. S., & Yudovskaya, M. A. (1994). Nuffieldite from the Maleevskoe massive sulfide deposit, Russia. The Canadian Mineralogist, 32(2), 359-364.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Nuffieldite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/nuffieldite-2941},
  note      = {Accessed 2026-05-11}
}