Orlandiite

Pb3Cl4(Se4+O3) · H2O
IMA status
  • Approved
IMA symbol
Ola
Discovered
1996
IMA approved
1998
Also known as
  • IMA1998-038
  • Orlandiiet

Where it forms, where it's found

Geological setting

Selenium-rich oxidized zone of a hydrothermal ore deposit.

Type locality
Baccu Locci Mine
  1. Villaputzu
  2. South Sardinia Province
  3. Sardinia
  4. Italy

39.5440°, 9.5345°

4recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Lustre
Vitreous to silky
Transparency
Translucent
Colour
Colourless to white
Streak
White
Tenacity
brittle
Cleavage
Perfect

Perfect (010)

Density
5.66 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.96
Surface relief
Very high
Principal indices
nβ 1.96
Dispersion
strong
UV response
None.
Notes

n = 1.96(5)

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 8.136(3) Å · b = 8.430(6) Å · c = 9.233(7) Å
Cell angles
α = 62.58(7) ° · β = 71.84(4) ° · γ = 75.13(4) °
Ratio a:b:c
1 : 1.036 : 1.135
Z
2
Morphology

Elongate tabular crystals.

Twinning

Invariably twinned on (010).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead3207.200621.600
68.43%
17ClChlorineChlorine435.450141.800
15.61%
34SeSeleniumSelenium178.97178.971
8.69%
8OOxygenOxygen415.99963.996
7.05%
1HHydrogenHydrogen21.0082.016
0.22%
Total908.383100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1998-038
  • Orlandiiet

In other languages

German
IMA 1998-038 · Orlandiit
Italian
Orlandiite

Classification

Strunz
10th ed.

4.JH.20

  • 4OxidesClass
  • 4.JArsenites, antimonites, bismuthites, sulfites, selenites, tellurites; iodatesDivision
  • 4.JHSelenites without additional anions, with H2OGroup
  • 4.JH.20OrlandiiteSpecies

Literature, links & citation

Citations
  1. 1999Campostrini, I., Gramaccioli, C. M., Demartin, F. (1999) Orlandiite, Pb3Cl4(SeO3)3•H2O, a new mineral species, and an associated lead-copper selenite chloride from the Baccu Locci mine, Sardinia, Italy. The Canadian Mineralogist, 37 (6) 1493-1498
  2. 2003Demartin, F., Gramaccioli, C. M., Pilati, T. (2003) The crystal structure of orlandiite, Pb3Cl4(SeO3)·H2O, a complex case of twinning and disorder. The Canadian Mineralogist, 41 (5) 1147-1153 doi:10.2113/gscanmin.41.5.1147 DOI: 10.2113/gscanmin.41.5.1147
  3. 2005(2005) Orlandiite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Orlandiite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/orlandiite-7056},
  note      = {Accessed 2026-05-11}
}