Otwayite

Ni2(CO3)(OH)2 · H2O
IMA status
  • Approved
IMA symbol
Otw
Discovered
1977
Also known as
  • IMA1976-028
  • Otwayiet

Where it forms, where it's found

Geological setting

Narrow veinlets to 1 mm in width, probably late-stage fracture filling, transecting nickeloan serpentine, millerite, polydymite, and apatite.

Type locality
Otway Ni deposit
  1. Nullagine
  2. East Pilbara Shire
  3. Western Australia
  4. Australia

-21.7361°, 120.0778°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent · Opaque
Colour
Green · bright green
Density
3.41 g/cm³

Optical

Optical type
Biaxial
Refractive index
1.65 – 1.72
Surface relief
High
Principal indices
nα 1.65 · nγ 1.72
Pleochroism
Weak

Deepest color normal to the fiber axis.

Dispersion
very strong
Michel-Lévy diagramhighlighted lineδ = 0.0700
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]700 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation700 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 10.18 Å · b = 27.4 Å · c = 3.22 Å
Ratio a:b:c
1 : 2.692 : 0.316
Unit cell volume
898.2 ų
Z
8
Type-locality form

Fibrous habit, rosette-like aggregates more or less normal to the veinlet walls.

Comment

Orthorhombic (?). Point Group: n.d.; Space Group: n.d.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
28NiNickelNickel258.693117.386
51.17%
8OOxygenOxygen615.99995.994
41.84%
6CCarbonCarbon112.01112.011
5.23%
1HHydrogenHydrogen41.0084.032
1.76%
Total229.423100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mg

Synonyms

  • IMA1976-028
  • Otwayiet

In other languages

German
IMA 1976-028 · Otwayit
Italian
Otwayite

Classification

Strunz
10th ed.

5.DA.15

  • 5CarbonatesClass
  • 5.DCarbonates with additional anions, with H2ODivision
  • 5.DAWith medium-sized cationsGroup
  • 5.DA.15OtwayiteSpecies
Dana
8th ed.

16b.03.02.01

  • 16bHydrated Carbonates Containing Hydroxyl or HalogenClass
  • 16b.03AmBn(XO3)pZqxH2O & with (m+n):p = 2:1Type
  • 16b.03.02— unnamed intermediate level —Group
  • 16b.03.02.01OtwayiteSpecies
CIM

11.14.5

  • 11CarbonatesClass
  • 11.14Carbonates of Co and NiGroup
  • 11.14.5OtwayiteSpecies

Literature, links & citation

Citations
  1. 1977Nickel, Ernest H., Robinson, Bruce W., Davis, Charles E. S., MacDonald, Robert D. (1977) Otwayite, a new nickel mineral from Western Australia. American Mineralogist, 62 (9-10) 999-1002
  2. 2005(2005) Otwayite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2006Frost, Ray L., Weier, Matt L., Martens, Wayde N., Mills, Stuart J. (2006) The hydroxylated nickel carbonates otwayite and paraotwayite – a SEM, EDX and vibrational spectroscopic study. Neues Jahrbuch für Mineralogie - Abhandlungen, 183 (1) 107-116 doi:10.1127/0077-7757/2006/0062DOI: 10.1127/0077-7757/2006/0062
  4. 2007Ercit, T. S., Piilonen, P. C., Rowe, R. (2007) NEW MINERAL NAMES. American Mineralogist, 92 (8) 1539-1542 doi:10.2138/am.2007.499 DOI: 10.2138/am.2007.499
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Otwayite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/otwayite-3044},
  note      = {Accessed 2026-05-11}
}