Paratooite-(La)

(La,Ca,Na,Sr)6Cu(CO3)8
IMA status
  • Approved
IMA symbol
Pto-La
IMA approved
2005
Also known as
  • IMA2005-020
  • Paratooiet-(La)

Where it forms, where it's found

Geological setting

Copper and REE deposit From type description: Formation took place under conditions of intense weathering in an arid climate, probably at neutral or slightly basic pH and oxidizing conditions, with evaporation of saline groundwaters playing an important role.

Type locality
Paratoo copper Mine
  1. Paratoo
  2. District Council of Peterborough
  3. South Australia
  4. Australia

-32.6795°, 139.3304°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Pale turquoise-blue to pale blue
Streak
Pale blue
Cleavage
None Observed

TEM studies indicate a cleavage parallel to (100)

Density
3.68 g/cm³

Optical

Optical type
Biaxial (-) · 2V calc = 72.6°
Refractive index
1.605 – 1.752
Surface relief
High
Principal indices
nα 1.605 · nβ 1.696 · nγ 1.752
Pleochroism
Visible

Medium strong; X = very pale bluish; Y = Z = bluish (with greenish tint).

UV response
No visible fluorescence
Notes

Absorption: Z ≈ Y >> X.

Michel-Lévy diagramhighlighted lineδ = 0.1470
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1470 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1470 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#59
Cell parameters
a = 7.2250(3) Å · b = 12.7626(5) Å · c = 10.0559(4) Å
Ratio a:b:c
1 : 1.766 : 1.392
Unit cell volume
927.25 ų
Type-locality form

Sheaves and radiating sprays of blade-like to tabular pale blue crystals in thin fissures in a slaty country rock. Individual crystals are typically 50-200 µm in maximum dimension but <5 µm thick.

Comment

Data from Krivovichev et al. (2019). Wallwork et al. (2006) gives the following unit-cell parameters, determined from synchrotron powder diffraction data (indexed on a primitive orthorhombic cell): a = 10.0862(5), b = 12.8088(6), c = 7.2360(4) Å, V = 934.8(1) Å3; they could not determine the crystal structure, but suggested several possible space groups.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
57LaLanthanumLanthanum6138.905833.430
36.53%
38SrStrontiumStrontium687.620525.720
23.05%
8OOxygenOxygen2415.999383.976
16.83%
20CaCalciumCalcium640.078240.468
10.54%
11NaSodiumSodium622.990137.940
6.05%
6CCarbonCarbon812.01196.088
4.21%
29CuCopperCopper163.54663.546
2.79%
Total2281.168100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2005-020
  • Paratooiet-(La)

In other languages

German
IMA 2005-020 · Paratooit-(La)
Italian
paratooite-(La)

Classification

Strunz
10th ed.

5.AD.20

  • 5CarbonatesClass
  • 5.ACarbonates without additional anions, without H2ODivision
  • 5.ADWith rare-earth elements (REE)Group
  • 5.AD.20Paratooite-(La)Species

Literature, links & citation

Citations
  1. 2006Pring, A., Wallwork, K., Brugger, J., U. Kolitsch, (2006) Paratooite-(La), a new lanthanum-dominant rare-earth copper carbonate from Paratoo, South Australia. Mineralogical Magazine, 70 (1) 131-138 doi:10.1180/0026461067010319DOI: 10.1180/0026461067010319
  2. 2006Piilonen, P. C.; Rowe, R.; Ercit, T.S.; Locock, A.J. (2006) New Mineral Names. American Mineralogist, 91 (8). 1452-1457 doi:10.2138/am.2006.470 DOI: 10.2138/am.2006.470
  3. 2015(2015) Paratooite-(La). Handbook of Mineralogy. Mineralogical Society of America
  4. 2019Krivovichev, Sergey V., Panikorovskii, Taras L., Zolotarev, Andrey A., Bocharov, Vladimir N., Kasatkin, Anatoly V., Škoda, Radek (2019) Jahn-Teller Distortion and Cation Ordering: The Crystal Structure of Paratooite-(La), a Superstructure of Carbocernaite. Minerals, 9 (6). 370 doi:10.3390/min9060370DOI: 10.3390/min9060370
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Paratooite-(La) — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/paratooite-la-27579},
  note      = {Accessed 2026-05-11}
}