Parawulffite

K5Na3Cu8O4(SO4)8
IMA status
  • Approved
IMA symbol
Pwlf
IMA approved
2013
Also known as
  • IMA2013-036
  • Parawulffiet

Where it forms, where it's found

Geological setting

Incrustations on basalt scoria and on hematite.

Type locality
Yadovitaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.8333°, 160.3333°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Dark green or deep emerald-green
Streak
Light green
Tenacity
brittle
Cleavage
Perfect

One parallel to elongation, second coplanar with (010).

Laminated fracture

Density
3.35 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.585 – 1.717
Surface relief
High
Principal indices
nα 1.585 · nγ 1.717
Pleochroism

Z = very strong, deep emerald-green; X = very pale green, almost colourless.

Notes

Absorption: Z > X. The perfect cleavage parallel to the elongation (causing laminated fracturing) and the very strong pleochroism prevented measurement of β and 2V values.

Michel-Lévy diagramhighlighted lineδ = 0.1320
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1320 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1320 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P2/c
Cell parameters
a = 13.904(1) Å · b = 4.9765(3) Å · c = 23.586(2) Å
Cell angles
γ = 90.209(6) °
Ratio a:b:c
1 : 0.358 : 1.696
Unit cell volume
1631.98 ų
Z
2
Morphology

Imperfect prismatic crystals up to 0.4 × 0.2 mm, in clusters and crusts; [010] elongation often observed; commonly curved, blocky character.

Type-locality form

Crude crystals or irregularly shaped grains.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3615.999575.964
35.88%
29CuCopperCopper863.546508.368
31.67%
16SSulfurSulfur832.060256.480
15.98%
19KPotassiumPotassium539.098195.490
12.18%
11NaSodiumSodium322.99068.970
4.29%
Total1605.272100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Rb
  • Cs

Synonyms

  • IMA2013-036
  • Parawulffiet

In other languages

German
IMA 2013-036 · Parawulffit
Italian
parawulffite

Classification

Strunz
10th ed.

7.BC.60

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.60ParawulffiteSpecies

Literature, links & citation

Citations
  1. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) New minerals and nomenclature modifications approved in 2013. CNMNC Newsletter No.17. Mineralogical Magazine, 77 (7) 2997-3005 doi:10.1180/minmag.2013.077.7.09DOI: 10.1180/minmag.2013.077.7.09
  2. 2014Pekov, I. V., Zubkova, N. V., Yapaskurt, V. O., Belakovskiy, D. I., Chukanov, N. V., Lykova, I. S., Savelyev, D. P., Sidorov, E. G., Pushcharovsky, D. Y. (2014) Wulffite, K3NaCu4O2(SO4)4, and parawulffite, K5Na3Cu8O4(SO4)8, two new minerals from fumarole sublimates of the Tolbachik Volcano, Kamchatka, Russia. The Canadian Mineralogist, 52 (4) 699-716 doi:10.3749/canmin.1400018 DOI: 10.3749/canmin.1400018
  3. 2016(2016) Parawulffite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Parawulffite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/parawulffite-43899},
  note      = {Accessed 2026-05-11}
}