Pellouxite

(Cu,Ag)2Pb21Sb23S55ClO
IMA status
  • Approved
IMA symbol
Plx
IMA approved
2001
Also known as
  • IMA2001-033
  • Pellouxiet

Where it forms, where it's found

Geological setting

Late extensional calcite veins in dolomitic limestones.

Type locality
Buca della Vena Mine
  1. Pontestazzemese
  2. Stazzema
  3. Lucca Province
  4. Tuscany
  5. Italy

43.9986°, 10.2944°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Opaque
Colour
Black
Streak
Brown
Tenacity
brittle
Cleavage
Distinct/Good

Good parallel to elongation.

Density
5.97 g/cm³

Optical

Optical colour
Black
Anisotropism
Distinct
Bireflectance
Weak, white to white-gray
Internal reflections
Red internal reflections at grain edges and defects
Tropism
Anisotropic
Reflectance R%
(40.5,25.9) 400, (40.7,24.2) 420, (39.4,23.8) 440, (38.8,24.3) 460, (38.3,23.8) 470, (38.9,23.6) 480, (38.2,23.0) 500, (38.3,22.9) 520, (37.4,22.6) 540, (37.3,22.4) 546, (37.4,22.1) 560, (37.0,21.4) 580, (36.9,21.5) 589, (36.2,21.2) 600, (35.8,20.7) 620, (35.3,19.9) 640, (35.2,19.6) 650, (35.2,19.8) 660, (34.1,19.6) 680, (33.6,19.3) 700, (33.6,18.0) 720, (32.5,17.9) 740, (32.1,17.1) 760, (30.9,16.3) 780, (30.0,16.0) 800
Notes

Anisotropy is described as distinct, but the reflectivity data only show one value each for in air and in oil.

Reflected-light panel
36.1 %anisotropic · dual curve
Specimen sRGB 214, 153, 87
White reference100 % reflector under same lamp
R₁ R₂
Mode
Bireflectance
Weak, white to white-gray
Anisotropism
Distinct
Reflected colour
Black
Internal reflections
Red internal reflections at grain edges and defects

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 55.824 Å · b = 4.0892 Å · c = 24.128 Å
Cell angles
β = 113.14 °
Ratio a:b:c
1 : 0.073 : 0.432
Unit cell volume
5065 ų
Z
2
Twinning

None observed.

Type-locality form

Black acicular crystals, flattened up to 1 mm long and less than 0.05 mm thick

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead21207.2004351.200
46.74%
51SbAntimonyAntimony23121.7602800.480
30.08%
16SSulfurSulfur5532.0601763.300
18.94%
47AgSilverSilver2107.868215.736
2.32%
29CuCopperCopper263.546127.092
1.37%
17ClChlorineChlorine135.45035.450
0.38%
8OOxygenOxygen115.99915.999
0.17%
Total9309.257100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2001-033
  • Pellouxiet

In other languages

German
IMA 2001-033 · Pellouxit
Italian
Pellouxite

Classification

Strunz
10th ed.

2.JB.35d

  • 2Sulfides and SulfosaltsClass
  • 2.JSulfosalts of PbS archetypeDivision
  • 2.JBGalena derivatives, with PbGroup
  • 2.JB.35dPellouxiteSpecies

Literature, links & citation

Citations
  1. 2004Orlandi, Paolo; Dini, Andrea (2004) Die Mineralien der Buca della Vena-Mine, Apuaner Berge, Toskana (Italien) [The minerals of the Buca della Vena mine, Apuan Mountains, Tuscany (Italy)]. Lapis, 29 (1). 11-24; 58
  2. 2004Orlandi, Paolo, Moëlo, Yves, Meerschaut, Alain, Palvadeau, Pierre, Leone, Philippe (2004) Lead-antimony sulfosalts from Tuscany (Italy) VI. Pellouxite, ~ (Cu,Ag)2Pb21Sb23S55ClO, a new oxy-chloro-sulfosalt from Buca della Vena mine, Apuan Alps. European Journal of Mineralogy, 16 (5) 839-844 doi:10.1127/0935-1221/2004/0016-0839 DOI: 10.1127/0935-1221/2004/0016-0839
  3. 2004Palvadeau, Pierre, Meerschaut, Alain, Orlandi, Paolo, Moëlo, Yves (2004) Lead-antimony sulfosalts from Tuscany (Italy) VII. Crystal structure of pellouxite, ~ (Cu,Ag)2Pb21Sb23S55ClO, an expanded monoclinic derivative of Ba12Bi24S48 hexagonal sub-type (zinkenite group) European Journal of Mineralogy, 16 (5) 845-855 doi:10.1127/0935-1221/2004/0016-0845DOI: 10.1127/0935-1221/2004/0016-0845
  4. 2014(2014) Pellouxite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pellouxite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pellouxite-25602},
  note      = {Accessed 2026-05-11}
}