Penriceite

[Mg(H2O)6][Na(H2O)2Al3(PO4)2F6] · H2O
IMA status
  • Approved
IMA symbol
Prc
Also known as
  • Penriceiet

Where it forms, where it's found

Geological setting

marbles; a secondary phase

Type locality
Penrice marble quarry
  1. Penrice
  2. Barossa Council
  3. South Australia
  4. Australia

-34.4817°, 139.0467°

2recorded occurrences
Source · OpenStreetMap

Physical

Density
2.12 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 10 – 20°
Refractive index
1.502 – 1.58
Surface relief
Moderate
Principal indices
nα 1.502 · nβ 1.503 · nγ 1.58
Birefringence
n<sub>γ</sub> was not measured in the type material, but is estimated here as derived from the 2V° measurement. The birefringence is subsequently calculated from this estimated n<sub>γ</sub>, and so should be considered as estimate as well.
Notes

nγ not determined due to extreme thinness of the crystals; orientation: X = b, Y ≈ c, Z ≈ a* An estimate of nγ is calculated here from the observations of B(+) and 2V° = 10°-20°.

Michel-Lévy diagramhighlighted lineδ = 0.0780
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]780 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation780 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 13.478(3) Å · b = 9.971(2) Å · c = 6.999(1) Å
Cell angles
β = 97.20(3) °
Ratio a:b:c
1 : 0.740 : 0.519
Type-locality form

platy crystals, up to 100 μm in diameter and 1-2 μm thick, forming rod-like aggregates

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1715.999271.983
45.77%
9FFluorineFluorine618.998113.988
19.18%
13AlAluminiumAluminium326.98280.946
13.62%
15PPhosphorusPhosphorus230.97461.948
10.42%
12MgMagnesiumMagnesium124.30524.305
4.09%
11NaSodiumSodium122.99022.990
3.87%
1HHydrogenHydrogen181.00818.144
3.05%
Total594.304100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Penriceiet

In other languages

German
IMA 2021-068 · Penriceit

Classification

Strunz
10th ed.

8.DM

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DMWith large and medium-sized cations, (OH, etc.):RO4 > 2:1Group
  • 8.DMPenriceiteSpecies

Group, growth & confusion

Commonly confused with
2 minerals

Literature, links & citation

Citations
  1. 2022Elliott, P., Grey, I.E., Macrae, C.M., Kampf, A.R., Davidson, C. (2022): Penriceite, [Mg(H2O)6][Na(H2O)2Al3(PO4)2F6]·H2O, the F-analogue of aldermanite, from the Penrice marble quarry. Australian Journal of Mineralogy, 23(1), 5-12.
  2. 2022(2022) Penriceite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Penriceite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/penriceite-55685},
  note      = {Accessed 2026-05-11}
}