Pentahydroborite

CaB2O(OH)6 · 2H2O
IMA status
  • Approved
IMA symbol
Phb
Discovered
1961
Also known as
  • Pentahydroboriet
  • Pentahydroborita

Where it forms, where it's found

Type locality
Novofrolovskoye B-Cu deposit
  1. Tur'insk
  2. Turya river
  3. Serovsky District
  4. Sverdlovsk Oblast
  5. Russia

59.7833°, 60.5000°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless
Streak
White
Cleavage
None Observed
Density
2.00 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 73 – 79°
Refractive index
1.532 – 1.546
Surface relief
Moderate
Principal indices
nα 1.531\0 – 1.532 · nβ 1.536 – 1.539 · nγ 1.542 – 1.546
Dispersion
r < v moderate
UV response
Violet in long wave UV
Michel-Lévy diagramhighlighted lineδ = 0.7780
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]7780 nmhigh order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation7780 nm
Orderhigh order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 7.845(4) Å · b = 6.525(5) Å · c = 8.124(5) Å
Cell angles
α = 111.62(5) ° · β = 111.19(4) ° · γ = 73.44(6) °
Ratio a:b:c
1 : 0.832 : 1.036
Z
2
Morphology

Anhedral granular.

Type-locality form

Small grains showing no crystal form

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
66.73%
20CaCalciumCalcium140.07840.078
18.58%
5BBoronBoron210.81021.620
10.02%
1HHydrogenHydrogen101.00810.080
4.67%
Total215.769100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Pentahydroboriet
  • Pentahydroborita

In other languages

German
Pentahydroborit
Italian
Pentahydroborite · Pentaidroborite

Classification

Strunz
10th ed.

6.BB.10

  • 6BoratesClass
  • 6.BDiboratesDivision
  • 6.BBNeso-diborates with double tetrahedra B2O(OH)6; 2(2T)Group
  • 6.BB.10PentahydroboriteSpecies
Dana
8th ed.

26.02.01.01

  • 26Hydrated Borates Containing Hydroxyl or HalogenClass
  • 26.02DiboratesType
  • 26.02.01— unnamed intermediate level —Group
  • 26.02.01.01PentahydroboriteSpecies
CIM

9.3.15

  • 9BoratesClass
  • 9.3Borates of Ca and SrGroup
  • 9.3.15PentahydroboriteSpecies

Literature, links & citation

Citations
  1. 1961Malinko, S.V. (1961) New boron minerals — uralborite and pentahydroborite. Zapiski Vsesoyuznogo Mineralogicheskogo Obshchestva: 90(6): 673-681.
  2. 1962Fleischer, Michael; František, Čech (1962) New mineral names. American Mineralogist, 47 (11-12). 1482-1485
  3. 1967IMA (1967) International Mineralogical Association: Commission on New Minerals and Mineral Names. Mineralogical Magazine and Journal of the Mineralogical Society, 36 (277) 131-136 doi:10.1180/minmag.1967.036.277.20 DOI: 10.1180/minmag.1967.036.277.20
  4. 1973Egorov-Tismenko, Y.K., Barishnikov, J.M., Shashkin, D.N., Simonov, M.A., Belov, N.V. (1973) The crystal structure of pentahydroborate CaB2O4·5H2O = Ca[B2O(OH)6]·2H2O. Soviet Physics - Doklady: 18: 102-103.
  5. 1977Kazanskaya, E.V., Chemodina, T.N., Egorov-Tismenko, Y.K., Simonov, M.A., Belov, N.V. (1977) Refined crystal structure of pentahydroborite Ca[B2O(OH)6]·2H2O. Soviet Physics - Crystallography: 22: 35-36.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pentahydroborite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pentahydroborite-3154},
  note      = {Accessed 2026-05-11}
}