Peretaite

CaSb3+4O4(SO4)2(OH)2 · 2H2O
IMA status
  • Approved
IMA symbol
Pta
Discovered
1979
IMA approved
1979
Also known as
  • IMA1979-068
  • Peretaiet

Where it forms, where it's found

Geological setting

Stibnite deposit in deeply silicified limestone. Formed by the action of sulfuric acid on stibnite in the presence of limestone.

Formed by the action of sulfuric acid on oxidizing stibnite deposits.

Type locality
Pereta Mine
  1. Scansano
  2. Grosseto Province
  3. Tuscany
  4. Italy

42.6433°, 11.3578°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless

Can be pink due to encrustations of valentinite.

Streak
White
Cleavage
Perfect

Perfect on (100).

Density
4.06 g/cm³

Optical

Optical type
Biaxial (+)
Refractive index
1.841 – 1.935
Surface relief
Very high
Principal indices
nα 1.841 · nγ 1.935
Dispersion
relatively strong
Extinction
Z = c; X ∧ b = ∼28°.
Notes

Beta not determined. 2V is very large.

Michel-Lévy diagramhighlighted lineδ = 0.0940
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]940 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation940 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
#10
Cell parameters
a = 24.665(4) Å · b = 5.6006(9) Å · c = 10.185(1) Å
Cell angles
β = 95.98(1) °
Ratio a:b:c
1 : 0.227 : 0.413
Z
4
Morphology

Divergent sprays of laths, botyroidal, massive. Crystals are flattened on (100) and often elongated along [001]. Forms include (100), (310), (110), (122), (001), (010), (210), (201), (302), and (601).

Twinning

Very common on (100).

Type-locality form

Aggregates of tabular crystals. The largest crystals have dimensions up to 5 x 2 x 0.5 mm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
51SbAntimonyAntimony4121.760487.040
57.08%
8OOxygenOxygen1615.999255.984
30.00%
16SSulfurSulfur232.06064.120
7.51%
20CaCalciumCalcium140.07840.078
4.70%
1HHydrogenHydrogen61.0086.048
0.71%
Total853.270100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1979-068
  • Peretaiet

In other languages

German
IMA1979-068 · Peretait
Italian
Peretaite

Classification

Strunz
10th ed.

7.DF.45

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DFWith large and medium-sized cationsGroup
  • 7.DF.45PeretaiteSpecies
Dana
8th ed.

31.06.04.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.06(AB)5(XO4)2Zq·xH2OType
  • 31.06.04— unnamed intermediate level —Group
  • 31.06.04.01PeretaiteSpecies
CIM

25.8.3

  • 25SulphatesClass
  • 25.8Sulphates of Sb, V, Cr and UGroup
  • 25.8.3PeretaiteSpecies

Group, growth & confusion

Often grow together
1 mineral

Literature, links & citation

Citations
  1. 1980Cipriani, Nicola, Menchetti, Silvio, Orlandi, Paolo, Sabelli, Cesare (1980) Peretaite, CaSb4O4(OH)2(SO4)2·2H2O, a new mineral from Pereta, Tuscany, Italy. American Mineralogist, 65 (9-10) 936-939
  2. 1980Menchetti, Silvio, Sabelli, Cesare (1980) Peretaite, CaSb4O4(OH)2(SO4)2·2H2O: its atomic arrangement and twinning. American Mineralogist, 65 (9-10) 940-946
  3. 2005(2005) Peretaite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2016Majzlan, Juraj, Števko, Martin, Lánczos, Tomáš (2016) Soluble secondary minerals of antimony in Pezinok and Kremnica (Slovakia) and the question of mobility or immobility of antimony in mine waters. Environmental Chemistry, 13 (6). 927-935 doi:10.1071/en16013 DOI: 10.1071/en16013
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Peretaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/peretaite-3159},
  note      = {Accessed 2026-05-11}
}