Perroudite

Ag4Hg5S5(I,Br)2Cl2
IMA status
  • Approved
IMA symbol
Pro
IMA approved
1986
Also known as
  • IMA1986-035
  • Perroudiet

Where it forms, where it's found

Geological setting

Oxidation zone of copper lead mine.

Supergene zone

Type locality
Cap Garonne Mine
  1. Le Pradet
  2. Toulon
  3. Var
  4. Provence-Alpes-Côte d'Azur
  5. France

43.0814°, 6.0322°

22recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Bright red
Streak
Reddish-orange
Tenacity
brittle
Cleavage
Perfect

(100)

Fracture
Irregular/Uneven
Density
6.75 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70°
Refractive index
2.3 – 2.4
Surface relief
Very high
Principal indices
nα 2.3 · nβ 2.4 · nγ 2.3
Pleochroism
Strong

Very intense. X = dark brownish red; Y = yellow; Z= brownish-yellow.

Dispersion
r > v, very strong.
Extinction
X = c; Y = b; Z = a.
Michel-Lévy diagramhighlighted lineδ = 0.0000
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]0 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation0 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
#43
Cell parameters
a = 17.47 Å · b = 12.23 Å · c = 4.29 Å
Ratio a:b:c
1 : 0.700 : 0.246
Unit cell volume
917.5 ų
Morphology

Prismatic on [001], flattened on (100). May have hollow terminations. Forms include are (100), (001), and minor (010) and {0hl}.

Twinning

Contact twinned 0hl?

Type-locality form

Fibrous tufted aggregates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
80HgMercuryMercury5200.5921002.960
48.24%
47AgSilverSilver4107.868431.472
20.75%
53IIodineIodine2126.904253.808
12.21%
16SSulfurSulfur532.060160.300
7.71%
35BrBromineBromine279.904159.808
7.68%
17ClChlorineChlorine235.45070.900
3.41%
Total2079.248100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1986-035
  • Perroudiet

In other languages

German
Perroudit
Spanish
Perroudita
Italian
Perroudite

Classification

Strunz
10th ed.

2.FC.20c

  • 2Sulfides and SulfosaltsClass
  • 2.FSulfides of arsenic, alkalies; sulfides with halide, oxide, hydroxide, H2ODivision
  • 2.FCWith Cl, Br, I (halide-sulfides)Group
  • 2.FC.20cPerrouditeSpecies
Dana
8th ed.

02.15.05.01

  • 02SulfidesClass
  • 02.15Chlor-sulfidesType
  • 02.15.05— unnamed intermediate level —Group
  • 02.15.05.01PerrouditeSpecies
CIM

6.5.7

  • 6Sulphosalts - Sulphostannates, Sulphogermanates,Sulpharsenates, Sulphantimonates, Sulphovanadates and SulphohalidesClass
  • 6.5SulphohalidesGroup
  • 6.5.7PerrouditeSpecies

Literature, links & citation

Citations
  1. 1987Sarp, Halil, Birch, William D., Hlava, Paul F., Pring, Allan, Sewell, David K. B., Nickel, Ernest H. (1987) Perroudite, a new sulfide-halide of Hg and Ag from Cap-Garonne, Var, France, and from Broken Hill, New South Wales, and Coppin Pool, Western Australia. American Mineralogist, 72 (11-12) 1251-1256
  2. 1987Mumme, William G., Nickel, Ernest H. (1987) Crystal structure and crystal chemistry of perroudite: A mineral from Coppin Pool, Western Australia. American Mineralogist, 72 (11-12) 1257-1262
  3. 2005Keller, Paul, Lissner, Falk, Schleid, Thomas (2005) Single-crystal structure determination of perroudite, Hg5Ag4S5(I, Br)2Cl2, from Tsumeb (Namibia), and its structural relationships to other sulfide halides of mercury and cinnabar. Neues Jahrbuch für Mineralogie - Abhandlungen, 181 (1) 1-9 doi:10.1127/0077-7757/2005/0181-0004DOI: 10.1127/0077-7757/2005/0181-0004
  4. 2021(2021) Perroudite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Perroudite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/perroudite-3169},
  note      = {Accessed 2026-05-11}
}