Phaunouxite

Ca3(AsO4)2 · 11H2O
IMA status
  • Approved
IMA symbol
Pnx
Discovered
1980
IMA approved
1980
Also known as
  • IMA1980-062
  • Phaunouxiet

Where it forms, where it's found

Type locality
Gabe Gottes Mine
  1. Sankt Jakob vein
  2. Neuenberg
  3. Sainte-Marie-aux-Mines
  4. Colmar-Ribeauvillé
  5. Haut-Rhin
  6. Grand Est
  7. France

48.2136°, 7.1589°

15recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
Colourless
Streak
White
Density
2.28 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 80° · 2V calc = 82°
Refractive index
1.532 – 1.556
Surface relief
Moderate
Principal indices
nα 1.532 · nβ 1.542 · nγ 1.556
Dispersion
weak
Michel-Lévy diagramhighlighted lineδ = 0.0240
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]240 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation240 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Cell parameters
a = 12.563(7) Å · b = 12.181(6) Å · c = 6.205(4) Å
Cell angles
α = 88.94(3) ° · β = 91.67(3) ° · γ = 113.44(3) °
Ratio a:b:c
1 : 0.970 : 0.494
Morphology

Acicular crystals, with forms (100) and (010).

Type-locality form

Acicular 1.5 mm crystals, often in fan-shaped aggregates.

Comment

Non-standard setting.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1915.999303.981
50.98%
33AsArsenicArsenic274.922149.844
25.13%
20CaCalciumCalcium340.078120.234
20.17%
1HHydrogenHydrogen221.00822.176
3.72%
Total596.235100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1980-062
  • Phaunouxiet

In other languages

German
IMA 1980-062 · Phaunouxit
Italian
Phaunouxite

Classification

Strunz
10th ed.

8.CJ.40

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CJWith only large cationsGroup
  • 8.CJ.40PhaunouxiteSpecies
Dana
8th ed.

40.03.12.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.03A3(XO4)2·xH2OType
  • 40.03.12— unnamed intermediate level —Group
  • 40.03.12.01PhaunouxiteSpecies
CIM

20.2.14

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.2Arsenates of Be, Mg, Ca or BaGroup
  • 20.2.14PhaunouxiteSpecies

Literature, links & citation

Citations
  1. 1982Bari, Hubert, Catti, Michele, Ferraris, Giovanni, Ivaldi, Gabriella, Permingeat, François (1982) Phaunouxite Ca3(AsO4)2 • 11 H2O, a new mineral strictly associated with rauenthalite. Bulletin de Minéralogie, 105 (4) 327-332 doi:10.3406/bulmi.1982.7624DOI: 10.3406/bulmi.1982.7624
  2. 1983Dunn, P. J.; Cabri, L. J.; Clark, A. M.; Fleischer, M. (1983) New mineral names. American Mineralogist, 68 (7-8). 849-852
  3. 1983Catti, M. & Ivaldi, G. (1983): On the topotactic dehydration Ca3(AsO4)2•11H2O (phaunouxite) —› Ca3(AsO4)2·10H2O (rauenthalite), and the structures of both minerals. Acta Crystallographica, B39, 4-10.
  4. 2005(2005) Phaunouxite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phaunouxite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phaunouxite-3186},
  note      = {Accessed 2026-05-11}
}