Philipsburgite

Cu5Zn(AsO4)(PO4)(OH)6 · H2O
IMA status
  • Approved
IMA symbol
Pbu
Discovered
1985
Also known as
  • IMA1984-029
  • Philipsburgiet
  • Unnamed (As/P-ordered P-rich "philipsburgite")

Where it forms, where it's found

Type locality
Black Pine Mine
  1. Philipsburg Mining District (Flint Creek Mining District)
  2. Granite County
  3. Montana
  4. USA

46.4478°, -113.3656°

33recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
Bright emerald green
Streak
Pale green
Cleavage
None Observed
Density
4.07 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 16° · 2V calc = 17°
Refractive index
1.729 – 1.775
Surface relief
High
Principal indices
nα 1.729 · nβ 1.774 · nγ 1.775
Pleochroism
Weak

Y=Z mediam green, X pale green

Dispersion
r < v
UV response
None observed
Michel-Lévy diagramhighlighted lineδ = 0.0460
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]460 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation460 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 12.3095(9) Å · b = 9.2276(3) Å · c = 10.7195(3) Å
Cell angles
β = 97.137(10) °
Ratio a:b:c
1 : 0.750 : 0.871
Z
4
Parting
None observed
Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper563.546317.730
43.11%
8OOxygenOxygen1515.999239.985
32.56%
33AsArsenicArsenic174.92274.922
10.17%
30ZnZincZinc165.38065.380
8.87%
15PPhosphorusPhosphorus130.97430.974
4.20%
1HHydrogenHydrogen81.0088.064
1.09%
Total737.055100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Zn
  • P

Synonyms

  • IMA1984-029
  • Philipsburgiet
  • Unnamed (As/P-ordered P-rich "philipsburgite")

In other languages

German
IMA 1984-029 · Philipsburgit
Italian
Philipsburgite

Classification

Strunz
10th ed.

8.DE.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DEWith only medium-sized cations, (OH, etc.):RO4 = 3:1Group
  • 8.DE.35PhilipsburgiteSpecies
Dana
8th ed.

42.02.04.02

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.02(AB)3(XO4)Zq·xH2OType
  • 42.02.04Kipushite GroupGroup
  • 42.02.04.02PhilipsburgiteSpecies
CIM

20.3.8

  • 20Arsenates (also arsenates with phosphate, but without other anions)Class
  • 20.3Arsenates of Zn, Cd or HgGroup
  • 20.3.8PhilipsburgiteSpecies

Literature, links & citation

Citations
  1. 1985Peacor, D.R., Dunn, P.J., Ramik, R.A., Sturman, B.D., Zeihen, L.G. (1985) Philipsburgite, a new copper zinc arsenate hydrate related to kipushite, from Montana. The Canadian Mineralogist: 23: 255-258.
  2. 1986Hawthorne, Frank C., Fleischer, Michael, Grew, Edward S., Grice, Joel D., Jambor, John L., Puziewicz, J., Roberts, Andrew C., Vanko, D. A., Zilczer, J. A. (1986) New mineral names. American Mineralogist, 71. 1277-1282
  3. 1988Sabelli, Cesare, Brizzi, Giancarlo, Olmi, Filippo (1988) Agardite-(Y), Gysinite-(Nd) and Other Rare Minerals from Sardinia [Italy]. The Mineralogical Record, 19 (5) 305-310
  4. 1988Braithwaite, R. S. W., Ryback, G. (1988) Philipsburgite from the Caldbeck Fells and Kipushite from Montana, and Their Infrared Spectra. Mineralogical Magazine, 52 (367) 529-533 doi:10.1180/minmag.1988.052.367.14DOI: 10.1180/minmag.1988.052.367.14
  5. 2005(2005) Philipsburgite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Philipsburgite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/philipsburgite-3191},
  note      = {Accessed 2026-05-11}
}