Philolithite

Pb12O6Mn7(SO4)(CO3)4Cl4(OH)12
IMA status
  • Approved
IMA symbol
Phi
Also known as
  • IMA1996-020
  • Philolithiet

Where it forms, where it's found

Type locality
Långban Mine
  1. Långban Ore District
  2. Filipstad
  3. Värmland County
  4. Sweden

59.8554°, 14.2648°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Adamantine
Colour
Pale to medium apple-green
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal
Density
5.91 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 60°
Refractive index
1.92 – 1.95
Surface relief
Very high
Principal indices
nα 1.92 · nβ 1.94 · nγ 1.95
Pleochroism
Weak

Very weak, pale green to yellow-green.

Dispersion
none
Extinction
X ∧ a = 45; Z = c.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0300
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]300 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation300 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Cell parameters
a = 12.627(9) Å · c = 12.595(9) Å
Z
2
Morphology

Simple tetragonal tablets dominated by the forms (001) and (111). Likely also (110) and (112).

Twinning

Sector twinning about the c-axis.

Type-locality form

Crust-like overgrowths on subhedral lead. Euhedral crystals perched on lead wires. Thin (< 1 mm), cleavable, fissure filling in a Mn-silicate-rich carbonate rock.

Comment

Space group P42/nnm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead12207.2002486.400
68.14%
8OOxygenOxygen3415.999543.966
14.91%
25MnManganeseManganese754.938384.566
10.54%
17ClChlorineChlorine435.450141.800
3.88%
6CCarbonCarbon412.01148.044
1.32%
16SSulfurSulfur132.06032.060
0.88%
1HHydrogenHydrogen121.00812.096
0.33%
Total3648.932100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1996-020
  • Philolithiet

In other languages

German
IMA 1996-020 · Philolithit
Italian
Filolitite · Philolithite

Classification

Strunz
10th ed.

5.BF.35

  • 5CarbonatesClass
  • 5.BCarbonates with additional anions, without H2ODivision
  • 5.BFWith (Cl), SO4, PO4, TeO3Group
  • 5.BF.35PhilolithiteSpecies

Literature, links & citation

Citations
  1. 1998Moore, Paul B., Kampf, Anthony R., Jonsson, Erik J., Swihart, George H. (1998) Philolithite, a New Mineral from Långban, Värmland, Sweden. The Mineralogical Record, 29 (3) 201-206
  2. 1999Jambor, J. L., Puziewicz, J., Roberts, A. C. (1999) New mineral names. American Mineralogist, 84 (4) 685-688
  3. 2000Moore, Paulus B., Kampf, Anthony R., Gupta, P.K. Sen (2000) The crystal structure of philolithite, a trellis-like open framework based on cubic closest-packing of anions. American Mineralogist, 85 (5) 810-816 doi:10.2138/am-2000-5-623 DOI: 10.2138/am-2000-5-623
  4. 2005(2005) Philolithite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Philolithite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/philolithite-7230},
  note      = {Accessed 2026-05-11}
}