Philoxenite

(K,Na,Pb)4(Na,Ca)2(Mg,Cu)3(Fe3+0.5Al0.5)(SO4)8
IMA status
  • Approved
IMA symbol
Pxn
IMA approved
2016
Also known as
  • IMA2015-108
  • Philoxeniet

Where it forms, where it's found

Geological setting

Fumarole at 250 C

Type locality
Yadovitaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.8333°, 160.3333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless to very pale yellowish
Streak
White
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.027 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 85°
Refractive index
1.562 – 1.58
Surface relief
Moderate
Principal indices
nα 1.562 · nβ 1.572 · nγ 1.580
Pleochroism
Non-pleochroic
Dispersion
Very strong, r > v
UV response
None
Michel-Lévy diagramhighlighted lineδ = 0.0180
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]180 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation180 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#1
Cell parameters
a = 8.8410(3) Å · b = 8.9971(3) Å · c = 16.1861(5) Å
Cell angles
α = 91.927(3) ° · β = 94.516(3) ° · γ = 90.118(3) °
Ratio a:b:c
1 : 1.018 : 1.831
Type-locality form

Isolated oblique-angled, pseudotrigonal or polygonal tabular crystals up to 0.3 × 0.6 mm.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead4207.200828.800
36.40%
8OOxygenOxygen3215.999511.968
22.49%
16SSulfurSulfur832.060256.480
11.27%
29CuCopperCopper363.546190.638
8.37%
19KPotassiumPotassium439.098156.392
6.87%
11NaSodiumSodium622.990137.940
6.06%
20CaCalciumCalcium240.07880.156
3.52%
12MgMagnesiumMagnesium324.30572.915
3.20%
26FeIronIron0.555.84527.922
1.23%
13AlAluminiumAluminium0.526.98213.491
0.59%
Total2276.702100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2015-108
  • Philoxeniet

In other languages

German
IMA 2015-108 · Philoxenit

Classification

Strunz
10th ed.

7.AC.60

  • 7SulfatesClass
  • 7.ASulfates (selenates, etc.) without additional anions, without H2ODivision
  • 7.ACWith medium-sized and large cationsGroup
  • 7.AC.60PhiloxeniteSpecies

Literature, links & citation

Citations
  1. 2016(2016)
  2. 2016Hålenius, U., Hatert, F., Pasero, M., Mills, S.J. (2016) New minerals and nomenclature modifications approved in 2016, CNMNC Newsletter no 30. Mineralogical Magazine, 80 (2) 407-413 doi:10.1180/minmag.2016.080.081DOI: 10.1180/minmag.2016.080.081
  3. 2020Pekov, I.V., Agakhanov, A.A., Zubkova, N.V., Belakovskiy, D.I., Vigasina, M.F., Britvin, S.N., Turchkova, A.G., Sidorov, E.G. (2020) Philoxenite, (K,Na,Pb)4(Na,Ca)2(Mg,Cu)3( Al0.5)(SO4)8, a new mineral from fumarole exhalations of the Tolbachik Volcano, Kamchatka, Russia. Notes of the Russian Mineralogical Society: 149(4): 67-77.
  4. 2022(2022) Philoxenite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Philoxenite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/philoxenite-47599},
  note      = {Accessed 2026-05-11}
}