Phosphofibrite

(H2O,K)3.5Fe3+8(PO4)6(OH)7 · 5H2O
IMA status
  • Approved
IMA symbol
Pfb
Discovered
1982
IMA approved
1982
Also known as
  • IMA1982-082
  • Phosphofibriet

Where it forms, where it's found

Type locality
Clara Mine
  1. Oberwolfach
  2. Ortenaukreis
  3. Freiburg Region
  4. Baden-Württemberg
  5. Germany

48.3797°, 8.2289°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Yellow to yellowish green

Optical

Optical type
Biaxial (-)
Refractive index
1.755 – 1.79
Surface relief
High
Principal indices
nα 1.755 · nγ 1.79
Dispersion
distinct to strong
Michel-Lévy diagramhighlighted lineδ = 0.0350
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]350 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation350 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 29.02 Å · b = 5.20 Å · c = 19.72 Å
Cell angles
β = 107.04 °
Ratio a:b:c
1 : 0.179 : 0.680
Z
4
Comment

Space group C2/c; refined from powder diffraction film data; originally assumed to be orthorhombic, space group Pbmn or Pnmn.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen39.515.999631.961
44.33%
26FeIronIron855.845446.760
31.34%
15PPhosphorusPhosphorus630.974185.844
13.03%
19KPotassiumPotassium3.539.098136.843
9.60%
1HHydrogenHydrogen241.00824.192
1.70%
Total1425.600100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1982-082
  • Phosphofibriet

In other languages

German
IMA1982-082 · Phosphofibrit
Spanish
Fosfofibrita
Italian
Fosfofibrite · Phosphofibrite

Classification

Strunz
10th ed.

8.DJ.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.DPhosphates, etc. with additional anions, with H2ODivision
  • 8.DJWith large and medium-sized cations, (OH, etc.):RO4 = 1:1Group
  • 8.DJ.20PhosphofibriteSpecies
Dana
8th ed.

42.13.14.03

  • 42Hydrated Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 42.13MiscellaneousType
  • 42.13.14— unnamed intermediate level —Group
  • 42.13.14.03PhosphofibriteSpecies
CIM

19.2.14

  • 19PhosphatesClass
  • 19.2Phosphates of CuGroup
  • 19.2.14PhosphofibriteSpecies

Literature, links & citation

Citations
  1. 1984Walenta, K. and Dunn, P. J. (1984): Phosphofibrit, ein neues Eisenphosphat aus der Grube Clara im mittleren Schwarzwald (BRD). Chemie der Erde, 43, 11-16. (in German).
  2. 1984American Mineralogist (1984): 69: 1192.
  3. 1999Kolitsch, U. (1999): Evidence for the identity of meurigite and phosphofibrite by transmission electron microscopy and X-ray powder diffraction. European Journal of Mineralogy: 11, Beih. no.1, 132.
  4. 2005(2005) Phosphofibrite. Handbook of Mineralogy. Mineralogical Society of America
  5. 2007Kampf, A. R., Pluth, J. J., Chen, Y.-S. (2007) The crystal structure of meurigite. American Mineralogist, 92 (8) 1518-1524 doi:10.2138/am.2007.2486 DOI: 10.2138/am.2007.2486
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phosphofibrite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phosphofibrite-3200},
  note      = {Accessed 2026-05-11}
}