Phosphophyllite

Zn2Fe2+(PO4)2 · 4H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Pp
Discovered
1920
Also known as
  • Phosphophylliet

Where it forms, where it's found

Geological setting

Granite pegmatite.

A secondary mineral in zoned complex granitic pegmatites. Also as an alteration product of sphalerite and Mn-Fe phosphates, in hydrothermal vein deposits.

Type locality
Hagendorf North Pegmatite
  1. Hagendorf
  2. Waidhaus
  3. Neustadt an der Waldnaab District
  4. Upper Palatinate
  5. Bavaria
  6. Germany

49.6553°, 12.4617°

29recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Bright blue-green to colourless · colourless in transmitted light.
Tenacity
brittle
Cleavage
Perfect

Perfect on (100), distinct on (010) and (102).

Density
3.08 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 44° · 2V calc = 34°
Refractive index
1.595 – 1.62
Surface relief
Moderate
Principal indices
nα 1.595 – 1.599 · nβ 1.614 – 1.617 · nγ 1.616 – 1.62
Birefringence
0.021
Pleochroism
Not Visible
Dispersion
r > v perceptible
Extinction
Y ∧ c = 50°; Z = b.
UV response
None.
Michel-Lévy diagramhighlighted lineδ = 0.0210
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]210 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation210 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 10.387(9) Å · b = 5.09(1) Å · c = 10.563(9) Å
Cell angles
β = 121.07(7) °
Ratio a:b:c
1 : 0.490 : 1.017
Z
2
Morphology

Thick tabular (100) to acutely terminated. Twinning common.

Twinning

Common on (100) giving fishtail twins; may be polysynthetic. Rarely on (102).

Type-locality form

Well formed crystals and druses.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
42.79%
30ZnZincZinc265.380130.760
29.15%
15PPhosphorusPhosphorus230.97461.948
13.81%
26FeIronIron155.84555.845
12.45%
1HHydrogenHydrogen81.0088.064
1.80%
Total448.605100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mn

Synonyms

  • Phosphophylliet

In other languages

French
Phosphophyllite
German
Phosphophyllit
Spanish
Fosfofilita
Italian
Fosfofillite
Portuguese
fosfofilita · fosfofilite
Japanese
フォスフォフィライト · りんようせき · 燐葉石
Chinese
磷叶石
Russian
Фосфофиллит
Arabic
فوسفوفيليت

Classification

Strunz
10th ed.

8.CA.40

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CAWith small and large/medium cationsGroup
  • 8.CA.40PhosphophylliteSpecies
Dana
8th ed.

40.02.07.01

  • 40Hydrated Normal Phosphates, Arsenates and VanadatesClass
  • 40.02AB2(XO4)2·xH2OType
  • 40.02.07— unnamed intermediate level —Group
  • 40.02.07.01PhosphophylliteSpecies
CIM

19.6.14

  • 19PhosphatesClass
  • 19.6Phosphates of ZnGroup
  • 19.6.14PhosphophylliteSpecies

Literature, links & citation

Citations
  1. 1915Laubmann, H.; Steinmetz, H. (1915) Phosphatführende Pegmatite des Oberpfälzer und Bayerischen Waldes. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 55 (1-6). 523-586 doi:10.1524/zkri.1915.55.1.523DOI: 10.1524/zkri.1915.55.1.523
  2. 1921Wherry, E.T., Gordon, S.G., Foshag, W.F. (1921) New minerals. American Mineralogist: 6: 63-68.
  3. 1926Steinmetz, H. (1926) Phosphophyllit und Reddingit von Hagendorf. Zeitschrift für Kristallographie, Mineralogie und Petrographie, 64 (1-6). 405-412 doi:10.1524/zkri.1926.64.1.405DOI: 10.1524/zkri.1926.64.1.405
  4. 1927Palache, Charles, Berman, Harry (1927) Crystallographic notes: 1. Phosphophyllite; 2. Hematite; 3. Willemite; 4. Hedyphane. American Mineralogist, 12 (4) 180-187
  5. 1928Foshag, W.F. (1928) New mineral names. American Mineralogist: 13: 32-34.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phosphophyllite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phosphophyllite-3181},
  note      = {Accessed 2026-05-11}
}