Phoxite

(NH4)2Mg2(C2O4)(PO3OH)2(H2O)4
IMA status
  • Approved
IMA symbol
Phx
IMA approved
2018
Also known as
  • IMA2018-009
  • Phoxiet
  • UM1977-10-PO:CaClKMg

Where it forms, where it's found

Geological setting

found in a hot and humid area of the mine in an unusual bat-guano-related, post-mining assemblage

Type locality
125 foot level
  1. Rowley Mine
  2. Theba
  3. Painted Rock Mining District
  4. Painted Rock Mountains
  5. Maricopa County
  6. Arizona
  7. USA

33.0492°, -113.0330°

2recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
colorless

light to medium brown or beige due to inclusions

Streak
white
Tenacity
brittle
Cleavage
Imperfect/Fair

fair (100)

Fracture
Irregular/Uneven
Density
1.98 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 16° · 2V calc = 17.2°
Refractive index
1.499 – 1.542
Surface relief
Moderate
Principal indices
nα 1.499 · nβ 1.541 · nγ 1.542
Birefringence
Slight r < v dispersion was observed.
Pleochroism
Non-pleochroic
Michel-Lévy diagramhighlighted lineδ = 0.0430
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]430 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation430 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
P21/c
Cell parameters
a = 7.2962(3) Å · b = 13.5993(4) Å · c = 7.8334(6) Å
Cell angles
β = 108.271(8) °
Ratio a:b:c
1 : 1.864 : 1.074
Z
2
Type-locality form

composite blades, up to about 0.4 mm in maximum dimension, growing in complex intergrowths

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
58.62%
15PPhosphorusPhosphorus230.97461.948
14.19%
12MgMagnesiumMagnesium224.30548.610
11.13%
7NNitrogenNitrogen214.00728.014
6.41%
6CCarbonCarbon212.01124.022
5.50%
1HHydrogenHydrogen181.00818.144
4.15%
Total436.722100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2018-009
  • Phoxiet
  • UM1977-10-PO:CaClKMg

In other languages

German
IMA 2018-009 · Phoxit

Classification

Strunz
10th ed.

10.AB.60

  • 10Organic CompoundsClass
  • 10.ASalts of organic acidsDivision
  • 10.ABOxalatesGroup
  • 10.AB.60PhoxiteSpecies

Literature, links & citation

Citations
  1. 2018Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2018) CNMNC Newsletter No 43, New minerals and nomenclature modifications approved in 2018. Mineralogical Magazine, 82 (3) 779-785 doi:10.1180/mgm.2018.72DOI: 10.1180/mgm.2018.72
  2. 2019Kampf, Anthony R., Celestian, Aaron J., Nash, Barbara P., Marty, Joe (2019) Phoxite, (NH4)2Mg2(C2O4)(PO3OH)2(H2O)4, the first phosphate-oxalate mineral. American Mineralogist, 104 (7) 973-979 doi:10.2138/am-2019-6991 DOI: 10.2138/am-2019-6991
  3. 2020(2020) Phoxite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phoxite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phoxite-52918},
  note      = {Accessed 2026-05-11}
}