Phyllotungstite

HCaFe3+3(WO4)6 · 10H2O
IMA status
  • Approved
IMA symbol
Ptgs
Discovered
1984
IMA approved
1984
Also known as
  • IMA1984-018
  • Phyllotungstiet

Where it forms, where it's found

Geological setting

Secondary mineral from the oxidized zone of a hydrothermal polymetallic deposit.

Type locality
Clara Mine
  1. Oberwolfach
  2. Ortenaukreis
  3. Freiburg Region
  4. Baden-Württemberg
  5. Germany

48.3797°, 8.2289°

2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Yellow
Cleavage
Perfect
Fracture
Irregular/Uneven
Density
5.26 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 18° · 2V calc = 16°
Refractive index
2.1 – 2.185
Surface relief
Very high
Principal indices
nα 2.10 · nβ 2.183 – 2.185 · nγ 2.185
Dispersion
r < v extreme
Michel-Lévy diagramhighlighted lineδ = 0.0850
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]850 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation850 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Hexagonal
Space group
#126
Cell parameters
a = 7.31(3) Å · c = 19.55(1) Å
Z
3
Morphology

Platy.

Twinning

On (110) (original orthorhomic description).

Type-locality form

Crusts, composed of tabular crystals and scaly, in part radial, aggregates. Crystals are up to 0.25 mm in size.

Comment

Originally given cell was orthorhombic, with 7.29, 12.59 and 19.55. Since the mineral is optically biaxial, the space group given by Grey (2006) might refer to an average cell (due to twinning?).

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
74WTungstenTungsten6183.8401103.040
58.80%
8OOxygenOxygen3415.999543.966
29.00%
26FeIronIron355.845167.535
8.93%
20CaCalciumCalcium140.07840.078
2.14%
1HHydrogenHydrogen211.00821.168
1.13%
Total1875.787100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1984-018
  • Phyllotungstiet

In other languages

German
Phyllotungstit
Italian
Fillotungstite · Phyllotungstite

Classification

Strunz
10th ed.

7.GB.20

  • 7SulfatesClass
  • 7.GMolybdates, Wolframates and NiobatesDivision
  • 7.GBWith additional anions and/or H2OGroup
  • 7.GB.20PhyllotungstiteSpecies
Dana
8th ed.

49.02.04.01

  • 49Hydrated Molybdates and TungstatesClass
  • 49.02Hydrated Normal Molybdates and TungstatesType
  • 49.02.04— unnamed intermediate level —Group
  • 49.02.04.01PhyllotungstiteSpecies
CIM

27.4.17

  • 27Sulphites, Chromates, Molybdates and TungstatesClass
  • 27.4TungstatesGroup
  • 27.4.17PhyllotungstiteSpecies

Literature, links & citation

Citations
  1. 1984Walenta, K. (1984) Phyllotungstit, ein neues sekundäres Wolframmineral aus der Grube Clara im mittleren Schwarzwald. Neues Jahrbuch für Mineralogie - Monatshefte, 1984. 529-535
  2. 1986Hawthorne, F.C., Dunn, P.J., Grice, J.D., Puziewicz, J., Shigley, J.E. (1986) New mineral names. American Mineralogist: 71: 845-847.
  3. 2005(2005) Phyllotungstite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2006Grey, Ian E., Birch, William D., Bougerol, Catherine, Mills, Stuart J. (2006) Unit-cell intergrowth of pyrochlore and hexagonal tungsten bronze structures in secondary tungsten minerals. Journal of Solid State Chemistry, 179. 3860-3869 doi:10.1016/j.jssc.2006.08.030DOI: 10.1016/j.jssc.2006.08.030
  5. 2007Birch, W. D., Grey, I. E., Mills, S. J., Bougerol, C., Pring, A., Ansermet, S. (2007) Pittongite, a new tungstate with a mixed-layer, pyrochlore hexagonal tungsten bronze structure, from Victoria, Australia. The Canadian Mineralogist, 45 (4) 857-864 doi:10.2113/gscanmin.45.4.857 DOI: 10.2113/gscanmin.45.4.857
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Phyllotungstite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/phyllotungstite-3203},
  note      = {Accessed 2026-05-11}
}