Piccoliite

NaCaMn3+2(AsO4)2O(OH)
IMA status
  • Approved
IMA symbol
Pcc
IMA approved
2017
Also known as
  • IMA2017-016
  • Piccoliiet
  • Unnamed (Ca-Na-Mn Arsenate)

Where it forms, where it's found

Geological setting

In Fe–Mn ore hosted in metaquartzites.

Type locality
Montaldo Mine (Montaldo di Mondovì Mine)
  1. Borgata Oberti
  2. Montaldo di Mondovì
  3. Cuneo Province
  4. Piedmont
  5. Italy

44.3189°, 7.8525°

2recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789105 – 5.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Black. It is transparent in thin section although very deep red coloured.
Streak
Brown
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
4.084 g/cm³

Optical

Optical colour
Grey.
Anisotropism
Distinct, in shades of grey.
Internal reflections
Common, in brownish tints.
Tropism
Anisotropic
Reflectance R%
(7.7, 9.8) 470, (7.7, 9.5) 546, (7.4, 9.3) 589, (7.4, 9.2) 650
UV response
Not fluorescent.
Notes

Calculated mean refractive index is 1.878.

Reflected-light panel
7.6 %anisotropic · dual curve
Specimen sRGB 104, 72, 37
White reference100 % reflector under same lamp
R₁ R₂
Mode
Anisotropism
Distinct, in shades of grey.
Reflected colour
Grey.
Internal reflections
Common, in brownish tints.

Crystallography

Crystal system
Orthorhombic
Space group
Pbcm
Cell parameters
a = 8.8761(9) Å · b = 7.5190(8) Å · c = 11.689(1) Å
Ratio a:b:c
1 : 0.847 : 1.317
Parting
None observed.
Type-locality form

Aggregates of black anhedral crystals, embedded in the quartz matrix, and rarely as black well-developed prisms.

Comment

Data above for Montaldo di Mondovì sample. a = 8.8889, b = 7.5269, c = 11.6795 Å for Valletta sample.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1015.999159.990
33.07%
33AsArsenicArsenic274.922149.844
30.97%
25MnManganeseManganese254.938109.876
22.71%
20CaCalciumCalcium140.07840.078
8.29%
11NaSodiumSodium122.99022.990
4.75%
1HHydrogenHydrogen11.0081.008
0.21%
Total483.786100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2017-016
  • Piccoliiet
  • Unnamed (Ca-Na-Mn Arsenate)

In other languages

German
IMA 2017-016 · Piccoliit

Classification

Strunz
10th ed.

8.BH.85

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BHWith medium-sized and large cations, (OH,etc.):RO4 = 1:1Group
  • 8.BH.85PiccoliiteSpecies

Literature, links & citation

Citations
  1. 2008Kolitsch, U. (2008) The crystal structure of a new Ca-Na-Mn3+-arsenate from a small metamorphic Mn deposit in Italy. Poster, 18th Annual V. M. Goldschmidt Conference, Vancouver, Canada, July 13-18, 2008 & abstract in Geochim. Cosmochim. Acta 72, Special Supplement 12S, A487 [as unnamed Ca-Na-Mn3+-arsenate]
  2. 2017Cámara, F., Biagioni, C., Ciriotti, M.E., Bosi, F., Kolitsch, U., Paar, W.H., Blass, G., Bittarello, E. (2017) Piccoliite, a new mineral of the pilawite group. Joint SIMP-SGI-AIV-SoGeI 2017 Conference "Geosciences: a tool in a changing world", Pisa, Italy, September 3-6, 2017, Abstract book: 120. http://www.socgeol.it/files/download/abstract%20book/abstract_book_pisa_2017_doi.pdf
  3. 2017Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2017) New minerals and nomenclature modifications approved in 2017, CNMNC Newsletter No 37. Mineralogical Magazine, 81 (3) 737-742 doi:10.1180/minmag.2017.081.039DOI: 10.1180/minmag.2017.081.039
  4. 2022(2022) Piccoliite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Piccoliite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/piccoliite-51847},
  note      = {Accessed 2026-05-11}
}