Pillaite

Pb9Sb10S23ClO0.5
IMA status
  • Approved
IMA symbol
Pil
IMA approved
1997
Also known as
  • IMA1997-042
  • Pillaiet

Where it forms, where it's found

Geological setting

Late extensional calcite veins embedded in dolomitic limestones.

Type locality
Buca della Vena Mine
  1. Pontestazzemese
  2. Stazzema
  3. Lucca Province
  4. Tuscany
  5. Italy

43.9986°, 10.2944°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Metallic
Transparency
Opaque
Colour
Black
Streak
Black to dark brown
Tenacity
brittle
Cleavage
None Observed

None

Fracture
Irregular/Uneven
Density
5.77 g/cm³

Optical

Pleochroism
Non-pleochroic
Anisotropism
weak
Bireflectance
weak
Internal reflections
Rare - red
Tropism
Anisotropic
Reflectance R%
(35.7) 470, (34.5) 546, (34.0) 589, (32.7) 650
Reflected-light panel
34.2 %isotropic · single curve
Specimen sRGB 207, 147, 83
White reference100 % reflector under same lamp
Bireflectance
weak
Anisotropism
weak
Internal reflections
Rare - red

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 49.65(3) Å · b = 4.150(4) Å · c = 21.91(1) Å
Cell angles
β = 99.76(5) °
Ratio a:b:c
1 : 0.084 : 0.441
Unit cell volume
4449 ų
Z
4
Type-locality form

Acicular [010] to 1 cm length and 0.1 mm thickness

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead9207.2001864.800
48.27%
51SbAntimonyAntimony10121.7601217.600
31.52%
16SSulfurSulfur2332.060737.380
19.09%
17ClChlorineChlorine135.45035.450
0.92%
8OOxygenOxygen0.515.9998.000
0.20%
Total3863.229100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1997-042
  • Pillaiet

In other languages

German
IMA 1997-042 · Pillait
Italian
Pillaite

Classification

Strunz
10th ed.

2.JB.35c

  • 2Sulfides and SulfosaltsClass
  • 2.JSulfosalts of PbS archetypeDivision
  • 2.JBGalena derivatives, with PbGroup
  • 2.JB.35cPillaiteSpecies

Literature, links & citation

Citations
  1. 2001Orlandi, Paolo, Moë lo, Yves, Meerschaut, Alain, Palvadeau, Pierre (2001) Lead-antimony sulfosalts from Tuscany (Italy) III. Pillaite, Pb9Sb10S23ClO0.5, a new Pb-Sb oxy-chloro-sulfosalt, from Buca della Vena mine. European Journal of Mineralogy, 13 (3) 605-610 doi:10.1127/0935-1221/2001/0013-0605 DOI: 10.1127/0935-1221/2001/0013-0605
  2. 2001Meerschaut, Alain, Palvadeau, Pierre, Moëlo, Yves, Orlandi, Paolo (2001) Lead-antimony sulfosalts from Tuscany (Italy) IV. Crystal structure of pillaite, Pb9Sb10S23ClO0.5, an expanded monoclinic derivative of hexagonal Bi(Bi2S3)9I3, from the zinkenite group. European Journal of Mineralogy, 13 (4) 779-790 doi:10.1127/0935-1221/2001/0013-0779DOI: 10.1127/0935-1221/2001/0013-0779
  3. 2012Kaden, R., Wagner, G., Bente, K. (2012) Crystal chemistry and electrical conductivity of boulangerite, dadsonite and iodine-substituted pillaite grown by chemical vapor transport. The Canadian Mineralogist, 50 (2) 219-233 doi:10.3749/canmin.50.2.219DOI: 10.3749/canmin.50.2.219
  4. 2021(2021) Pillaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pillaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pillaite-10318},
  note      = {Accessed 2026-05-11}
}