Piypite

K4Cu4O2(SO4)4 · (Na,Cu)Cl
IMA status
  • Approved
IMA symbol
Piy
Discovered
1982
IMA approved
1982
Also known as
  • Caratiite
  • IMA1982-097
  • Piypiet

Where it forms, where it's found

Geological setting

Fumarole at 500 C.

Type locality
Great Fissure eruption (Main Fracture)
  1. Tolbachik Volcanic field
  2. Milkovsky District
  3. Kamchatka Krai
  4. Russia

55.8333°, 160.3333°

5recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent · Translucent
Colour
Emerald green · dark green · black
Streak
Yellowish green
Tenacity
brittle
Cleavage
Perfect

Perfect cleavage parallel to elongation faces

Density
3.09 g/cm³

Optical

Optical type
Uniaxial (+)
Refractive index
1.583 – 1.711
Surface relief
Moderate
Principal indices
nω 1.583 – 1.598 · nε 1.695 – 1.711
Pleochroism
Visible

O = pale green, yellowish green; E = deep green, pale yellowish green

Michel-Lévy diagramhighlighted lineδ = 0.1125
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1125 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1125 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#129
Cell parameters
a = 13.63(3) Å · c = 4.96(2) Å
Z
4
Twinning

Assumed found in crystal structure analysis.

Type-locality form

Moss-like aggregates of imperfect long columnar or acicular crystals up to 3-cm long and 1-mm across, often empty inside.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper563.546317.730
33.49%
8OOxygenOxygen1815.999287.982
30.35%
19KPotassiumPotassium439.098156.392
16.48%
16SSulfurSulfur432.060128.240
13.52%
17ClChlorineChlorine135.45035.450
3.74%
11NaSodiumSodium122.99022.990
2.42%
Total948.784100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Caratiite
  • IMA1982-097
  • Piypiet

In other languages

German
Caratiit · IMA 1982-097 · Piypit
Italian
Piypite
Japanese
ピウパイト
Chinese
綠銅鉀石

Classification

Strunz
10th ed.

7.BC.40

  • 7SulfatesClass
  • 7.BSulfates (selenates, etc.) with additional anions, without H2ODivision
  • 7.BCWith medium-sized and large cationsGroup
  • 7.BC.40PiypiteSpecies
Dana
8th ed.

30.02.07.01

  • 30Anhydrous Sulfates Containing Hydroxyl or HalogenClass
  • 30.02(AB)2(XO4)ZqType
  • 30.02.07— unnamed intermediate level —Group
  • 30.02.07.01PiypiteSpecies
CIM

25.2.13

  • 25SulphatesClass
  • 25.2Sulphates of Cu and AgGroup
  • 25.2.13PiypiteSpecies

Literature, links & citation

Citations
  1. Transactions of the Russian Academy of Sciences/Earth Science Sections: 275: 108-110.
  2. 1984Vergasova L.P., Filatov S.K., Serafimova E.K., Stalova G.L. (1984) Piypite K2Cu2O(SO4)2 - a new mineral of volcanic sublimates. Doklady USSR Academy of Sciences, Earth Science Sections: 275: 714-717.
  3. 1984Vergasova, L.P., Filatov, S.K., Serafimova, E.K. (1984) Doklady USSR Academy of Sciences, Earth Science Sections: 275: 741.
  4. 1984Clark, A. M., Fejer, E. E., Couper, A. G. (1984) Caratiite, a potassium, new sulphate-chloride of copper and from the lavas of the 1869 Vesuvius eruption. Mineralogical Magazine, 48 (349) 537-539 doi:10.1180/minmag.1984.048.349.09 DOI: 10.1180/minmag.1984.048.349.09
  5. 1984Effenberger, Herta, Zemann, Josef (1984) The crystal structure of caratiite. Mineralogical Magazine, 48 (349) 541-546 doi:10.1180/minmag.1984.048.349.10 DOI: 10.1180/minmag.1984.048.349.10
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Piypite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/piypite-3225},
  note      = {Accessed 2026-05-11}
}