Playfairite

Pb16(Sb,As)19S44Cl
IMA status
  • Approved
IMA symbol
Pyf
Discovered
1966
IMA approved
1966
Also known as
  • IMA1966-019
  • Playfairiet

Where it forms, where it's found

Geological setting

Dolomitic and calcitic marbles. Coating sulfosalt minerals.

Type locality
Taylor Pit
  1. Madoc
  2. Centre Hastings Municipality
  3. Hastings County
  4. Ontario
  5. Canada

44.5022°, -77.4664°

3recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5 – 4/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Opaque
Colour
Lead gray to black
Streak
Black
Cleavage
Perfect

on (100)

Density
5.72 g/cm³

Optical

Pleochroism
Strong

White to brownish gray

UV response
Not fluorescent in UV

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 45.12 Å · b = 8.29 Å · c = 21.45 Å
Cell angles
β = 92.53 °
Ratio a:b:c
1 : 0.184 : 0.475
Z
4
Morphology

Tabular crystals

Twinning

Very fine twin lamellae

Type-locality form

Tabular crystals

Comment

Point Group: 2, m, or 2/m; Space Group: P2, Pm, P2/m, P21 or P21/m

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
82PbLeadLead16207.2003315.200
39.01%
51SbAntimonyAntimony19121.7602313.440
27.22%
33AsArsenicArsenic1974.9221423.518
16.75%
16SSulfurSulfur4432.0601410.640
16.60%
17ClChlorineChlorine135.45035.450
0.42%
Total8498.248100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • As

Synonyms

  • IMA1966-019
  • Playfairiet

In other languages

German
IMA 1966-019 · Playfairit
Italian
Playfairite

Classification

Strunz
10th ed.

2.LB.30

  • 2Sulfides and SulfosaltsClass
  • 2.LUnclassified SulfosaltsDivision
  • 2.LBWith essential PbGroup
  • 2.LB.30PlayfairiteSpecies
Dana
8th ed.

03.06.04.01

  • 03SulfosaltsClass
  • 03.062 < ø < 2.49Type
  • 03.06.04— unnamed intermediate level —Group
  • 03.06.04.01PlayfairiteSpecies
CIM

5.6.12

  • 5Sulphosalts - Sulpharsenites and Sulphobismuthites (those containing Sn, Ge,or V are in Section 6)Class
  • 5.6Sulpharsenites etc. of Pb aloneGroup
  • 5.6.12PlayfairiteSpecies

Literature, links & citation

Citations
  1. Y. Moëlo et al. (1987): Playfairite (chlorosulfosel de plomb) du gisement des Cougnasses (Hautes Alpes). Bull. Soc. Fr. Minéral. Cristallogr., xx, xx-xx.
  2. 1967Jambor, John Leslie (1967) New lead sulfantimonides from Madoc, Ontario. Part 1. The Canadian Mineralogist, 9 (1) 7-24
  3. 1967Jambor, John Leslie (1967) New lead sulfantimonides from Madoc, Ontario. Part 2 - mineral descriptions. The Canadian Mineralogist, 9 (2) 191-213
  4. 1968Jambor, John Leslie (1968) New lead sulfantimonides from Madoc, Ontario. Part 3--Syntheses, paragenesis, origin. The Canadian Mineralogist, 9 (4). 505-521
  5. 1981Breskovska, Vesselina V., Mozgova, Nadejda N., Bortnikov, Nicolay S., Gorshkov, Anatoly I., Tzepin, Anatoly I. (1981) New data on chlorine sulfosalts. Bulletin de Minéralogie, 104 (6) 757-762 doi:10.3406/bulmi.1981.7521DOI: 10.3406/bulmi.1981.7521
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Playfairite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/playfairite-3239},
  note      = {Accessed 2026-05-11}
}