Polyarsite

Na7CaMgCu2(AsO4)4F2Cl
IMA status
  • Approved
IMA symbol
Par
Also known as
  • Polyarsiet

Where it forms, where it's found

Geological setting

The fumaroles located here belong to the oxidizing type due to the mixing of hot (up to 500 °C) volcanic gas with atmospheric oxygen. The temperatures measured with the use of a chromel-alumel thermocouple in these pockets immediately after the opening were 300–350 °C

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Transparency
Transparent
Colour
sky-blue to light blue
Streak
white
Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
3.592 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 70° · 2V calc = 75°
Refractive index
1.624 – 1.682
Surface relief
High
Principal indices
nα 1.624 · nβ 1.645 · nγ 1.682
Pleochroism
Visible

Pleochroism is distinct: Z (turquoise-blue) > Y (light turquoise-blue) > X (pale bluish to colourless).

Dispersion
Dispersion of optical axes is weak, r > v.
Michel-Lévy diagramhighlighted lineδ = 0.0580
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]580 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation580 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 8.4323(4) Å · b = 10.0974(4) Å · c = 10.7099(6) Å
Cell angles
β = 90.822(4) °
Ratio a:b:c
1 : 1.197 : 1.270
Z
2
Parting
none
Type-locality form

short-prismatic, equant or tabular crystals up to 0.15 mm across, their clusters up to 0.3 mm in size or crusts up to 0.5 mm across and up to 0.03 mm thick.

Comment

The space group is I2/m

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
33AsArsenicArsenic474.922299.688
30.53%
8OOxygenOxygen1615.999255.984
26.08%
11NaSodiumSodium722.990160.930
16.40%
29CuCopperCopper263.546127.092
12.95%
20CaCalciumCalcium140.07840.078
4.08%
9FFluorineFluorine218.99837.996
3.87%
17ClChlorineChlorine135.45035.450
3.61%
12MgMagnesiumMagnesium124.30524.305
2.48%
Total981.523100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Polyarsiet

In other languages

German
IMA 2019-058 · Polyarsit

Classification

Strunz
10th ed.

8.BG.35

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BGWith medium-sized and large cations, (OH, etc.):RO4 = 0.5:1Group
  • 8.BG.35PolyarsiteSpecies

Literature, links & citation

Citations
  1. 2020Miyawaki, Ritsuro, Hatert, Frédéric, Pasero, Marco, Mills, Stuart J. (2020) IMA Commission on New Minerals, Nomenclature and Classification (CNMNC) - Newsletter 52. European Journal of Mineralogy, 32 (1) 1-11 doi:10.5194/ejm-32-1-2020 DOI: 10.5194/ejm-32-1-2020
  2. 2022(2022) Polyarsite. Handbook of Mineralogy. Mineralogical Society of America
  3. 2026Pekov, Igor V.; Zubkova, Natalia V.; Agakhanov, Atali A.; Belakovskiy, Dmitry I.; Vigasina, Marina F.; Yapaskurt, Vasiliy O.; Britvin, Sergey N.; Turchkova, Anna G.; Sidorov, Evgeny G.; Zhitova, Elena S.; et al. (2026) Polyarsite, Na7CaMgCu2(AsO4)4F2Cl, a New Mineral with Unique Complex Layers in the Novel-Type Crystal Structure. Minerals, 16 (2). doi:10.3390/min16020122DOI: 10.3390/min16020122
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Polyarsite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/polyarsite-54025},
  note      = {Accessed 2026-05-11}
}