Popovite

Cu5O2(AsO4)2
IMA status
  • Approved
IMA symbol
Ppv
IMA approved
2013
Also known as
  • IMA2013-060
  • Popoviet

Where it forms, where it's found

Geological setting

Fumeroles

Type locality
Arsenatnaya fumarole
  1. Second scoria cone
  2. Northern Breakthrough (North Breach)
  3. Great Fissure eruption (Main Fracture)
  4. Tolbachik Volcanic field
  5. Milkovsky District
  6. Kamchatka Krai
  7. Russia

55.6833°, 160.2333°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789103.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
olive green to dark olive-green

fine-grained varieties are light yellow-green

Tenacity
brittle
Cleavage
None Observed
Fracture
Irregular/Uneven
Density
5.30 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 50°
Refractive index
1.84 – 1.96
Surface relief
Very high
Principal indices
nα 1.84 · nβ 1.86 · nγ 1.96
Michel-Lévy diagramhighlighted lineδ = 0.1200
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]1200 nm3rd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation1200 nm
Order3rd order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
#2
Cell parameters
a = 5.1450(3) Å · b = 6.2557(3) Å · c = 6.2766(4) Å
Cell angles
α = 100.064(5) ° · β = 96.351(5) ° · γ = 95.100(5) °
Ratio a:b:c
1 : 1.216 : 1.220
Z
1
Type-locality form

prismatic or tabular crystals and as grains up to 0.2 mm in size forming clusters up to 1.5 mm in size and as crusts on basalt scoria or on aphthitalite incrustations

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
29CuCopperCopper563.546317.730
50.63%
8OOxygenOxygen1015.999159.990
25.49%
33AsArsenicArsenic274.922149.844
23.88%
Total627.564100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2013-060
  • Popoviet

In other languages

German
IMA 2013-060 · Popovit
Italian
popovite

Classification

Strunz
10th ed.

8.BB.55

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BBWith only medium-sized cations, (OH, etc.):RO4 about 1:1Group
  • 8.BB.55PopoviteSpecies

Literature, links & citation

Citations
  1. 2013Williams, P. A., Hatert, F., Pasero, M., Mills, S. J. (2013) New minerals and nomenclature modifications approved in 2013. CNMNC Newsletter No.17. Mineralogical Magazine, 77 (7) 2997-3005 doi:10.1180/minmag.2013.077.7.09DOI: 10.1180/minmag.2013.077.7.09
  2. 2015Pekov, Igor V., Zubkova, Natalia V., Yapaskurt, Vasiliy O., Belakovskiy, Dmitry I., Vigasina, Marina F., Sidorov, Evgeny G., Pushcharovsky, Dmitry Yu. (2015) New arsenate minerals from the Arsenatnaya fumarole, Tolbachik volcano, Kamchatka, Russia. III. Popovite, Cu5O2(AsO4)2. Mineralogical Magazine, 79 (1) 133-143 doi:10.1180/minmag.2015.079.1.11 DOI: 10.1180/minmag.2015.079.1.11
  3. 2016(2016) Popovite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Popovite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/popovite-43937},
  note      = {Accessed 2026-05-11}
}