Pseudocotunnite

K2PbCl4 (?)
IMA status
  • Approved
  • Grandfathered
  • Questionable
IMA symbol
Pcot
Discovered
1873
Also known as
  • Mellonite
  • Pseudocotunnia
  • Pseudocotunniet

Where it forms, where it's found

Geological setting

Active volcanic fumaroles.

Type locality
Mount Vesuvius
  1. Metropolitan City of Naples
  2. Campania
  3. Italy
1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Colour
Colourless · white

Optical

Optical type
Biaxial
Refractive index
2
Surface relief
Very high
Principal indices
nβ 2
Dispersion
relatively weak

Crystallography

Crystal system
Orthorhombic
Cell parameters
a = 9.82 Å · b = 11.8 Å · c = 5.77 Å
Ratio a:b:c
1 : 1.202 : 0.588
Morphology

Crystals flattened on (010) or (100), with indistinct {hk0} and {0kl} faces; elongated [001] into needle-like or lath-like shapes. <g>Verruciform</g> aggregates and dendritic crusts.

Comment

Probably orthorhombic (synthetic crystals have space group Pnma).

Synonyms

  • Mellonite
  • Pseudocotunnia
  • Pseudocotunniet

In other languages

German
Pseudocotunnit
Italian
pseudocotunnite

Classification

Strunz
10th ed.

3.AA.90

  • 3HalidesClass
  • 3.ASimple halides, without H2ODivision
  • 3.AAM:X = 1:1, 2:3, 3:5, etc.Group
  • 3.AA.90PseudocotunniteSpecies
Dana
8th ed.

11.02.01.01

  • 11Halide ComplexesClass
  • 11.02AmBX4Type
  • 11.02.01— unnamed intermediate level —Group
  • 11.02.01.01PseudocotunniteSpecies
CIM

8.8.12

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.8Halides of PbGroup
  • 8.8.12PseudocotunniteSpecies

Literature, links & citation

Citations
  1. 1873Scacchi, A. (1873): Contribuzioni mineralogiche per servire alla storia dell'incendio vesuviano del mese di aprile 1872 (parte seconda). Rendiconti della Reale Accademia delle Scienze Fisiche e Matematiche di Napoli, Serie 1, 6, 69 pp.
  2. 1873Scacchi, A. (1873): Acc. Napoli Att.: 6: no. 9 (as Pseudocotunnia).
  3. 1873Palmieri (1873) Reale accademia delle scienze fisische e matematiche, Naples, Rend.: 92 (as Pseudocotunnite).
  4. 1906Lorenz & Ruckstuhl (1906): Zeitschrift für anorganische und allgemeine Chemie, 51, 70-80.
  5. 1927Pelloux, A. (1927) The minerals of Vesuvius. American Mineralogist: 12: 14-19.
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Pseudocotunnite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/pseudocotunnite-3303},
  note      = {Accessed 2026-05-11}
}