Punkaruaivite

Li{Ti2(OH)2[Si4O11(OH)]} · H2O
IMA status
  • Approved
IMA symbol
Pka
IMA approved
2008
Also known as
  • IMA2008-018
  • Punkaruaiviet

Where it forms, where it's found

Geological setting

ussingite - aegirine - microcline vein in nepheline syenite. Rare late-stage hydrothermal minerals formed as a result of the alteration of earlier titanosilicates

Type locality
Eveslogchorr Mt
  1. Murmansk Oblast
  2. Russia

67.6790°, 33.9450°

4recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789104.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent · Translucent
Colour
brownish yellow to colorless
Streak
White
Tenacity
brittle
Cleavage
Perfect

(100)

Fracture
Step-Like
Density
2.60 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 85° · 2V calc = 82°
Refractive index
1.658 – 1.726
Surface relief
High
Principal indices
nα 1.658 · nβ 1.696 · nγ 1.726
Pleochroism
Weak

Y light brownish yellow, X brownish yellow

Dispersion
none
Michel-Lévy diagramhighlighted lineδ = 0.0680
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]680 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation680 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 26.68 Å · b = 8.75 Å · c = 5.24 Å
Cell angles
β = 91.2 °
Ratio a:b:c
1 : 0.328 : 0.196
Z
4
Type-locality form

well-shaped prismatic crystals flattened on (100) and elongate along [001] arranged in sheaf-like and radiating aggregates.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1515.999239.985
52.17%
14SiSiliconSilicon428.085112.340
24.42%
22TiTitaniumTitanium247.86795.734
20.81%
3LiLithiumLithium16.9406.940
1.51%
1HHydrogenHydrogen51.0085.040
1.09%
Total460.039100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2008-018
  • Punkaruaiviet

In other languages

German
IMA 2008-018 · Punkaruaivit
Italian
punkaruaivite

Classification

Strunz
10th ed.

9.DB.15

  • 9SilicatesClass
  • 9.DInosilicatesDivision
  • 9.DBInosilicates with 2-periodic single chains, Si2O6; Pyroxene-related mineralsGroup
  • 9.DB.15PunkaruaiviteSpecies

Literature, links & citation

Citations
  1. 2000Kolitsch, U., Pushcharovsky, D. Yu., Pekov, I. V., Tillmanns, E. (2000) A new, lintisite-related titanosilicate mineral from Russia: crystal structure, occurrence and properties. Poster, XIXth European Crystallographic Meeting (ECM 19), Nancy, August 25-31, 2000; abstract in Abstracts Book, 363 and Acta Crystallogr. A56 (Supplement), s363.
  2. 2010Yakovenchuk, V. N., Ivanyuk, G. Y., Pakhomovsky, Y. A., Selivanova, E. A., Men'Shikov, Y. P., Korchak, J. A., Krivovichev, S. V., Spiridonova, D. V., Zalkind, O. A. (2010) Punkaruaivite, LiTi2[Si4O11(OH)]2·H2O, a new mineral species from hydrothermal assemblages, Khibiny and Lovozero alkaline massifs, Kola Peninsula, Russia. The Canadian Mineralogist, 48 (1) 41-50 doi:10.3749/canmin.48.1.41 DOI: 10.3749/canmin.48.1.41
  3. 2011(2011) Punkaruaivite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Punkaruaivite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/punkaruaivite-38697},
  note      = {Accessed 2026-05-11}
}