Reppiaite

Mn2+5(VO4)2(OH)4
IMA status
  • Approved
IMA symbol
Rep
Discovered
1991
IMA approved
1991
Also known as
  • IMA1991-007
  • Reppiaiet

Where it forms, where it's found

Geological setting

Fractures cutting manganese-bearing cherts.

Type locality
Gambatesa Mine
  1. Reppia
  2. Ne
  3. Genoa
  4. Liguria
  5. Italy

44.3597°, 9.4500°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Orange-red
Streak
Yellow-red
Density
3.92 g/cm³

Optical

Optical type
Biaxial (-)
Refractive index
1.803 – 1.81
Surface relief
Very high
Principal indices
nα 1.803 · nγ 1.810
Pleochroism
Weak

yellow-orange to deep orange.

Dispersion
relatively strong
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0070
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]70 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation70 nm
Order1st order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/m
Cell parameters
a = 9.614(4) Å · b = 9.561(3) Å · c = 5.396(3) Å
Cell angles
β = 98.39(1) °
Ratio a:b:c
1 : 0.994 : 0.561
Z
2
Type-locality form

Minute tabular crystals, flattened on (100), with and irregular contour. The crystals are at most 50 µm thick and 300 µm in diameter. Under a polarizing microscope, the crystals commonly appear as fine-grained aggregates, with size of individual grains under 10 µm.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
25MnManganeseManganese554.938274.690
47.97%
8OOxygenOxygen1215.999191.988
33.53%
23VVanadiumVanadium250.942101.884
17.79%
1HHydrogenHydrogen41.0084.032
0.71%
Total572.594100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • As

Synonyms

  • IMA1991-007
  • Reppiaiet

In other languages

German
IMA 1991-007 · Reppiait
Italian
Reppiaite

Classification

Strunz
10th ed.

8.BD.20

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.BPhosphates, etc., with additional anions, without H2ODivision
  • 8.BDWith only medium-sized cations, (OH, etc.):RO4= 2:1Group
  • 8.BD.20ReppiaiteSpecies
Dana
8th ed.

41.04.08.01

  • 41Anhydrous Phosphates, Etc.containing Hydroxyl or HalogenClass
  • 41.04(AB)5(XO4)2ZqType
  • 41.04.08— unnamed intermediate level —Group
  • 41.04.08.01ReppiaiteSpecies

Literature, links & citation

Citations
  1. 1992Basso, R., Lucchetti, G., Zefiro, L., Palenzona, A. (1992) Reppiaite, Mn5(OH)4(VO4)2, a new mineral from Val Graveglia (Northern Apennines, Italy) Zeitschrift für Kristallographie - Crystalline Materials, 201 (14) 223-234 doi:10.1524/zkri.1992.201.14.223 DOI: 10.1524/zkri.1992.201.14.223
  2. 1993Jambor, L., Puziewicz, Jacek (1993) New Mineral Names. American Mineralogist, 78 (3-4) 450-455
  3. 1996Barbier, Jacques (1996) The crystal structure of Ni5(AsO4)2(OH)4 and its comparison to other M5(XO4)2(OH)4 compounds. European Journal of Mineralogy, 8 (1) 77-84 doi:10.1127/ejm/8/1/0077DOI: 10.1127/ejm/8/1/0077
  4. 1997Mandarino, Joseph A. (1997) New Minerals 1990-1994. The Mineralogical Record Inc., Tuscon, Arizona. 220pp.
  5. 2005(2005) Reppiaite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Reppiaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/reppiaite-3390},
  note      = {Accessed 2026-05-11}
}