Riotintoite

Al(SO4)(OH) · 3H2O
IMA status
  • Approved
IMA symbol
Rio
IMA approved
2015
Also known as
  • IMA2015-085
  • Riotintoiet

Where it forms, where it's found

Geological setting

Secondary mineral occurring in thin fissures in strongly altered dacitic-andesitic volcanic breccias.

Type locality
La Vendida Mine
  1. Sierra Gorda
  2. Antofagasta Province
  3. Antofagasta
  4. Chile

-22.8767°, -69.3411°

1recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless
Streak
White
Tenacity
brittle
Cleavage
Distinct/Good

Three good cleavages: (010), (001), and (201).

Density
2.13 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 62° · 2V calc = 67°
Refractive index
1.513 – 1.526
Surface relief
Moderate
Principal indices
nα 1.513 · nβ 1.522 · nγ 1.526
Dispersion
Weak, r > v.
Extinction
X ∧ b = 41°; Y ∧ c = 45°; Z ∧ a = 44°.
Michel-Lévy diagramhighlighted lineδ = 0.0130
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]130 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation130 nm
Order1st order
XPL colour

Crystallography

Crystal system
Triclinic
Space group
P1
Cell parameters
a = 5.600(2) Å · b = 7.450(3) Å · c = 7.671(3) Å
Cell angles
α = 74.785(7) ° · β = 86.042(8) ° · γ = 75.810(7) °
Ratio a:b:c
1 : 1.330 : 1.370
Unit cell volume
299.4 ų
Z
2
Morphology

Platy to tabular crystals. Forms observed: (010) (the major form), (001), (100), (110), (011), (120), (210), (123), (123), (131), and (131).

Type-locality form

Platy crystals up to 0.1 × 0.4 × 0.4 mm in size. Crystals occur lining cavities and are intergrown in veins up to several millimeters thick and two or more centimeters across.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen815.999127.992
65.94%
16SSulfurSulfur132.06032.060
16.52%
13AlAluminiumAluminium126.98226.982
13.90%
1HHydrogenHydrogen71.0087.056
3.64%
Total194.090100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA2015-085
  • Riotintoiet

In other languages

German
IMA 2015-085 · Riotintoit

Classification

Strunz
10th ed.

7.DC.45

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DCWith only medium-sized cations; chains of edge-sharing octahedraGroup
  • 7.DC.45RiotintoiteSpecies

Literature, links & citation

Citations
  1. 2016Hålenius, U., Hatert, F., Pasero, M., Mills, S. J. (2016) New minerals and nomenclature modifications approved in 2015 and 2016, CNMNC Newsletter No 29. Mineralogical Magazine, 80 (1) 199-205 doi:10.1180/minmag.2016.080.080DOI: 10.1180/minmag.2016.080.080
  2. 2016Chukanov, Nikita V., Aksenov, Sergey M., Rastsvetaeva, Ramiza K., Kampf, Anthony R., Möhn, Gerhard, Belakovskiy, Dmitriy I., Lorenz, Joachim A. (2016) Riotintoite, Al(SO4)(OH)·3H2O, A New Mineral From La Vendida Copper Mine, Antofagasta Region, Chile. The Canadian Mineralogist, 54 (5) 1293-1305 doi:10.3749/canmin.1500111DOI: 10.3749/canmin.1500111
  3. 2018(2018) Riotintoite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Riotintoite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/riotintoite-46850},
  note      = {Accessed 2026-05-11}
}