Rokühnite

FeCl2 · 2H2O
IMA status
  • Approved
IMA symbol
Rok
Also known as
  • IMA1979-036
  • Rokühniet

Where it forms, where it's found

Geological setting

Secondary, in fissures within earlier K-rich salt beds.

Type locality
Salzdetfurth Potash Works
  1. Bad Salzdetfurth
  2. Hildesheim District
  3. Lower Saxony
  4. Germany

52.0618°, 9.9986°

6recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent
Colour
Colourless (transmitted light) · light green

Brown when oxidized.

Tenacity
flexible
Cleavage
Very Good

(100); also good on (010)

Density
2.35 g/cm³

Optical

Optical type
Biaxial (+) · 2V measured = 64° · 2V calc = 68°
Refractive index
1.605 – 1.702
Surface relief
High
Principal indices
nα 1.605 · nβ 1.633 · nγ 1.702
Dispersion
strong (r ≤ v)
Michel-Lévy diagramhighlighted lineδ = 0.0970
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]970 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation970 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Cell parameters
a = 7.396(1) Å · b = 8.458(2) Å · c = 3.638(1) Å
Cell angles
β = 97.68(2) °
Ratio a:b:c
1 : 1.144 : 0.492
Z
2
Twinning

Contact, on (201).

Type-locality form

Rare thin plates, commonly comprising fibers, with dominating (110) form and a number of other forms present, up to 300 µm.

Comment

space group C2/m, C2 or Cm

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine235.45070.900
43.56%
26FeIronIron155.84555.845
34.31%
8OOxygenOxygen215.99931.998
19.66%
1HHydrogenHydrogen41.0084.032
2.47%
Total162.775100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Impurities
  • Mg

Synonyms

  • IMA1979-036
  • Rokühniet

In other languages

German
IMA 1979-036 · Rokühnit
Italian
Rokühnite

Classification

Strunz
10th ed.

3.BB.10

  • 3HalidesClass
  • 3.BSimple halides, with H2ODivision
  • 3.BBM:X = 1:2Group
  • 3.BB.10RokühniteSpecies
Dana
8th ed.

09.02.04.01

  • 09Normal HalidesClass
  • 09.02AX2Type
  • 09.02.04— unnamed intermediate level —Group
  • 09.02.04.01RokühniteSpecies
CIM

8.11.3

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.11Halides of Fe and NiGroup
  • 8.11.3RokühniteSpecies

Literature, links & citation

Citations
  1. 1965Morosin, B., Graeber, E.J. (1965) Crystal Structures of Manganese(II) and Iron(II) Chloride Dihydrate. Journal of Chemical Physics, 42, 898-901.
  2. 1976Schneider, W., Weitzel, H. (1976) Bestimmung der magnetischen phasen von eisen(II)-chlorid-doppelhydrat, FeCl2·2H2O, und kobalt(II)-chlorid-doppelhydrat, CoCl2·2H2O, mit neutronenbeugung. Acta Crystallographica, A32, 32-37.
  3. 1980von Hodenberg, R., von Struensee, G. (1980) Rokühnite, FeCl2•2H2O, a new mineral. Neues Jahrbuch für Mineralogie, Monatshefte: 125-130.
  4. 1980von Hodenberg, R., von Struensee, G. (1980) Rokühnite, FeCl2•2H2O, a new mineral. Neues Jahrb. Mineral. Monatsh.: 125-130.
  5. 1981Fleischer, Michael, Chao, George Y., Francis, Carl A., Pabst, and Adolf (1981) New Mineral Names. American Mineralogist, 66 (1-2) 217-220
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Rokühnite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/rokuhnite-3440},
  note      = {Accessed 2026-05-11}
}