Rollandite

Cu3(AsO4)2 · 4H2O
IMA status
  • Approved
IMA symbol
Rol
IMA approved
1998
Also known as
  • IMA1998-001
  • Rollandiet

Where it forms, where it's found

Type locality
Roua Mines (Clue de Roua)
  1. Daluis
  2. Nice Arrondissement
  3. Alpes-Maritimes
  4. Provence-Alpes-Côte d'Azur
  5. France

44.0304°, 6.8677°

1recorded occurrences
Source · OpenStreetMap

Safety & handling

Physical

Hardness
123456789104 – 4.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Lustre
Vitreous
Transparency
Transparent
Colour
Glass-green
Streak
Very light green
Tenacity
brittle
Cleavage
Distinct/Good

(001) good

Fracture
Conchoidal
Density
3.9 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 71° · 2V calc = 70°
Refractive index
1.745 – 1.76
Surface relief
High
Principal indices
nα 1.745 · nβ 1.755 · nγ 1.760
Pleochroism
Non-pleochroic
Dispersion
strong , r < v.
UV response
Not fluorescent
Michel-Lévy diagramhighlighted lineδ = 0.0150
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]150 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation150 nm
Order1st order
XPL colour

Crystallography

Crystal system
Orthorhombic
Space group
Pnma
Cell parameters
a = 5.6906(4) Å · b = 17.061(1) Å · c = 9.732(1) Å
Ratio a:b:c
1 : 2.998 : 1.710
Z
4
Twinning

None observed

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1215.999191.988
35.52%
29CuCopperCopper363.546190.638
35.27%
33AsArsenicArsenic274.922149.844
27.72%
1HHydrogenHydrogen81.0088.064
1.49%
Total540.534100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1998-001
  • Rollandiet

In other languages

French
Rollandite
German
IMA 1998-001 · Rollandit
Italian
Rollandite

Classification

Strunz
10th ed.

8.CD.30

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CDWith only medium-sized cations, RO4:H2O = 1:2Group
  • 8.CD.30RollanditeSpecies

Literature, links & citation

Citations
  1. 2000Sarp, Halil, Černý, Radovan (2000) Rollandite, Cu3(AsO4)2 · 4H2O, a new mineral: its description and crystal structure. European Journal of Mineralogy, 12 (5) 1045-1050 doi:10.1127/0935-1221/2000/0012-1045 DOI: 10.1127/0935-1221/2000/0012-1045
  2. 2001Jambor, J. L., Roberts, A. C. (2001) New mineral names. American Mineralogist, 86 (5) 767-770
  3. 2001Mandarino, Joseph A. (2001) New minerals. The Canadian Mineralogist, 39 (5) 1473-1502 doi:10.2113/gscanmin.39.5.1473 DOI: 10.2113/gscanmin.39.5.1473
  4. 2020Kornyakov, I. V.; Krivovichev, S. V. (2020) Hydrogen bonding and structural complexity of cornetite, cornubite, rollandite, and yvonite: a theoretical study. Zapiski RMO (Proceedings of the Russian Mineralogical Society), 149 (2). 80-95 doi:10.31857/s0869605520020033DOI: 10.31857/s0869605520020033
  5. 2021(2021) Rollandite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Rollandite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/rollandite-7037},
  note      = {Accessed 2026-05-11}
}