Rosenbergite

AlF[F0.5(H2O)0.5]4 · H2O
IMA status
  • Approved
IMA symbol
Ros
Discovered
1992
IMA approved
1992
Also known as
  • IMA1992-046

Where it forms, where it's found

Geological setting

In cavities in highly silicified limestones at the Cetine Mine, Tuscany, Itally; and as a sublimate from fumaroles in the crater of Mt. Erebus, Ross Island, Antarctica (Co-Type Localities.0

Type locality
Le Cetine di Cotorniano mine
  1. Chiusdino
  2. Siena Province
  3. Tuscany
  4. Italy

43.2320°, 11.1683°

6recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103 – 3.5/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless
Streak
Colroless
Tenacity
brittle
Cleavage
Distinct/Good

Good on (001).

Fracture
Irregular/Uneven
Density
2.1 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.403 – 1.427
Surface relief
Low
Principal indices
nω 1.427 · nε 1.403
Michel-Lévy diagramhighlighted lineδ = 0.0240
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]240 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation240 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
#138
Cell parameters
a = 7.715 Å · c = 3.648 Å
Z
2
Morphology

Tetragonal prisms approx. 0.25 mm in size; found as aggregates of microscopic crystals.

Twinning

None reported.

Type-locality form

radiating tufts

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
9FFluorineFluorine318.99856.994
41.29%
8OOxygenOxygen315.99947.997
34.78%
13AlAluminiumAluminium126.98226.982
19.55%
1HHydrogenHydrogen61.0086.048
4.38%
Total138.021100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1992-046

In other languages

French
Rosenbergite
German
IMA 1992-046 · Rosenbergit
Italian
Rosenbergite

Classification

Strunz
10th ed.

3.CD.05

  • 3HalidesClass
  • 3.CComplex halidesDivision
  • 3.CDIno-aluminofluoridesGroup
  • 3.CD.05RosenbergiteSpecies
Dana
8th ed.

09.03.06.01

  • 09Normal HalidesClass
  • 09.03AX3Type
  • 09.03.06— unnamed intermediate level —Group
  • 09.03.06.01RosenbergiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1993Olmi, Filippo, Sabelli, Cesare, Trosti-Ferroni, Renza (1993) Rosenbergite, AlF[F0.5(H2O)0.5]4·H2O, a new mineral from the Cetine mine (Tuscany, Italy): description and crystal structure. European Journal of Mineralogy, 5 (6) 1167-1174 doi:10.1127/ejm/5/6/1167 DOI: 10.1127/ejm/5/6/1167
  2. 1997Gaines, Richard V.; Skinner, H. Catherine W.; Foord, Eugene E.; Mason, Brian; Rosenzweig, Abraham; King, Vandall T. (1997) Dana's New Mineralogy (8th ed.). Wiley-Interscience. 1872 pp.
  3. 2005(2005) Rosenbergite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Rosenbergite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/rosenbergite-3453},
  note      = {Accessed 2026-05-11}
}