Rouvilleite

Na3Ca2(CO3)3F
IMA status
  • Approved
IMA symbol
Rvl
Discovered
1991
Also known as
  • IMA1989-050
  • Rouvilleiet
  • Unnamed (MSH UK-62)

Where it forms, where it's found

Geological setting

In a sodalite syenite inclusion within nepheline syenite.

Type locality
Poudrette quarry (De-Mix quarry
  1. Demix quarry
  2. Uni-Mix quarry
  3. Carrière Mont Saint-Hilaire
  4. MSH)
  5. Mont Saint-Hilaire
  6. La Vallée-du-Richelieu RCM
  7. Montérégie
  8. Québec
  9. Canada

45.5628°, -73.1417°

3recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789103/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colorless to pale tan

Commonly appears reddish-brown due to inclusions of kupletskite.

Streak
White
Tenacity
brittle
Cleavage

Good on (001) and imperfect on (010).

Fracture
Irregular/Uneven
Density
2.67 g/cm³

Optical

Optical type
Biaxial (-) · 2V measured = 25 – 30° · 2V calc = 28°
Refractive index
1.472 – 1.569
Surface relief
Moderate
Principal indices
nα 1.472 · nβ 1.562 · nγ 1.569
Birefringence
b = Y; c ∧ X = 6°, in the acute β angle.
Pleochroism
Non-pleochroic
Dispersion
None. Type description gives weak, r > v.
UV response
Not fluorescent.
Michel-Lévy diagramhighlighted lineδ = 0.0970
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]970 nm2nd order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation970 nm
Order2nd order
XPL colour

Crystallography

Crystal system
Monoclinic
Space group
C2/c
Cell parameters
a = 8.04 Å · b = 15.81 Å · c = 7.03 Å
Cell angles
β = 101.16 °
Ratio a:b:c
1 : 1.966 : 0.874
Morphology

Type material: Prismatic, elongate along [001], with forms (010), (110), (100), (101), (023) and (032). Also simpler crystals showing (010), (110), (100), and (001).

Type-locality form

Irregular crystalline masses up to 3 mm across, and rarely as euhedral crystals up to 1 mm across within cavities. Has been found within villiaumite; kupletskite has been found included within rouvilleite.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen915.999143.991
41.36%
20CaCalciumCalcium240.07880.156
23.02%
11NaSodiumSodium322.99068.970
19.81%
6CCarbonCarbon312.01136.033
10.35%
9FFluorineFluorine118.99818.998
5.46%
Total348.148100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1989-050
  • Rouvilleiet
  • Unnamed (MSH UK-62)

In other languages

German
IMA 1989-050 · Rouvilleit
Italian
Rouvilleite

Classification

Strunz
10th ed.

5.BC.10

  • 5CarbonatesClass
  • 5.BCarbonates with additional anions, without H2ODivision
  • 5.BCWith alkali-earth cationsGroup
  • 5.BC.10RouvilleiteSpecies
Dana
8th ed.

16a.05.05.01

  • 16aAnhydrous Carbonates Containing Hydroxyl or HalogenClass
  • 16a.05MiscellaneousType
  • 16a.05.05— unnamed intermediate level —Group
  • 16a.05.05.01RouvilleiteSpecies
CIM

12.1.3

  • 12Carbonates with other anionsClass
  • 12.1Carbonates with halidesGroup
  • 12.1.3RouvilleiteSpecies

Literature, links & citation

Citations
  1. 1991McDonald, Andrew M., Chao, George Y., Ramik, Robert A. (1991) Rouvilleite, a new sodium calcium fluorocarbonate mineral from Mont Saint-Hilaire, Quebec. The Canadian Mineralogist, 29 (1) 107-111
  2. 1991Khomyakov, A.P., Polezhaeva, L.I., Rogachev, D.L., Yamnova, N.A., and Pusharovsky, D.Yu. (1991) New natural fluorocarbonate Na2Ca(Mn,Ca)(CO3)3F, from the Lovozero alkaline massif. (Rouvilleite) Vestnik Moskovskogo Universiteta, Seriya Geologia, 1, 85-88 (in Russian).
  3. 1991Yamnova, N.A., Pusharovsky, D.Yu., Khomyakov, A.P. and Vyatkin, S.V. (1991) Crystallographic structure of the natural fluorocarbonate Na3Ca(Mn,Ca)(CO3)3F. [Rouvillite] Kristallografia, 36, 30-33. (in Russian)
  4. 2005(2005) Rouvilleite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Rouvilleite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/rouvilleite-3465},
  note      = {Accessed 2026-05-11}
}