Salammoniac

(NH4)Cl
IMA status
  • Approved
  • Grandfathered
IMA symbol
Sam
Also known as
  • Ammoniumchlorid
  • Chlorammonio
  • Chlorammonium
  • +10 more

Where it forms, where it's found

Geological setting

Volcanic fumaroles; burning coal seams; guano deposits.

111recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789101 – 2/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Colourless · White · sometimes yellow or brown.
Tenacity
sectile
Cleavage
Very Good

Imperfect on (111).

Fracture
Conchoidal
Density
1.532 g/cm³

Optical

Optical type
Isotropic
Surface relief
Moderate
Principal indices
n 1.639
Notes

Weakly birefringent at times, especially after mechanical deformation.

Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.639

Crystallography

Crystal system
Isometric
Cell parameters
a = 3.8756 Å
Z
1
Morphology

Crystals usually trapezohedral (112) modified by (113) at times; less commonly with gyroidal forms alone, or in combination. Dodecahedral; cubic (rare). Crystals often exhibit curved or stepped faces and may present a tetragnal or rhombohedral appearance due to suppression of faces and distortion. Skeletal or dendritic aggregates. Crusts or stalactitic masses; fibrous, earthy or mealy.

Twinning

On (111).

Parting
Translation gliding with T(011), t[001].
Comment

Space Group: Pm3m (synthetic).

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
17ClChlorineChlorine135.45035.450
66.27%
7NNitrogenNitrogen114.00714.007
26.19%
1HHydrogenHydrogen41.0084.032
7.54%
Total53.489100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Ammoniumchlorid
  • Chlorammonio
  • Chlorammonium
  • Chloride of Ammonium
  • Chlorure d'ammonium
  • Muriate of Ammonia
  • Natürliches Salmiak
  • Sal Ammoniac
  • Sal ammoniacus
  • Sal-Ammoniac
  • Salammoniak
  • Salmiakk
  • Sel ammoniac

In other languages

French
Salmiac
German
Salmiak
Spanish
Sal amoniaca · Sal amoniacal · Sal amoniaco · Sal de amoníaco
Italian
Clorammonio
Portuguese
sal amoníaco
Japanese
塩化アンモン石 · 塩化アンモン鉱
Chinese
卤砂 · 硇砂
Simplified Chinese
卤砂
Traditional Chinese
滷砂
Russian
Нашатырь
Arabic
ملح النشادر · 🜹

Classification

Strunz
10th ed.

3.AA.25

  • 3HalidesClass
  • 3.ASimple halides, without H2ODivision
  • 3.AAM:X = 1:1, 2:3, 3:5, etc.Group
  • 3.AA.25SalammoniacSpecies
Dana
8th ed.

09.01.03.01

  • 09Normal HalidesClass
  • 09.01AXType
  • 09.01.03— unnamed intermediate level —Group
  • 09.01.03.01SalammoniacSpecies
CIM

8.1.7

  • 8Halides - Fluorides, Chlorides, Bromides and Iodides; also Fluoborates and FluosilicatesClass
  • 8.1Halides of the alkali metals and ammoniumGroup
  • 8.1.7SalammoniacSpecies

Literature, links & citation

Citations
  1. 1556Agricola G (1556) Sal-ammoniac. in De Re Metallica, translated by Hoover H C and Hoover L H 1950, Dover (New York) 560-560
  2. 1747Wallerius, J.G. (1747) in Mineralogia, eller Mineralriket, (Stockholm).
  3. 1758Model, G. (1758) Versuche und Gedanken über ein natürliches und gewachsenes Salmiak, Leipzig 1758
  4. 1802Klaproth, M. H. (1802) LXXIX~ Untersuchung des natürlichen Salmiaks. In Beiträge zur chemischen Kenntniss der Mineralkörper Vol. 3. Rottmann. p.89-94.
  5. 1855Rammelsberg (1855) 41 (das Chlorammonium).
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Salammoniac — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/salammoniac-3507},
  note      = {Accessed 2026-05-11}
}