Santabarbaraite

Fe3+3(PO4)2(OH)3 · 5H2O
IMA status
  • Approved
IMA symbol
Sbb
IMA approved
2000
Also known as
  • Bosphorite
  • IMA2000-052
  • Oxykerchenite
  • +1 more

Where it forms, where it's found

Geological setting

In clays, pseudomorphous after vivianite

Type locality
Santa Barbara lignite district (Santa Barbara lignite basin
  1. Cavriglia lignite basin
  2. San Giovanni Valdarno lignite basin)
  3. Upper Valdarno (Upper Val d'Arno)
  4. Tuscany
  5. Italy
18recorded occurrences
Source · OpenStreetMap

Physical

Transparency
Transparent · Translucent
Colour
Orange · orange brown · yellowish-brown
Streak
yellow to yellowish-brown
Tenacity
brittle
Cleavage
None Observed
Fracture
Conchoidal
Density
2.42 g/cm³

Optical

Optical type
Isotropic
Surface relief
High
Principal indices
n 1.695
Birefringence
0.000
UV response
Not fluorescent in UV
Isotropy testPPL ↔ XPL diagnostic
PPL intrinsic colour; no change on stage rotation
XPL extinct at every orientation
Single index
n = 1.695

Crystallography

Crystal system
Amorphous
Morphology

Pseudomorphs of vivianite or botryoidal crusts.

Parting
parting according to the vivianite cleavage
Type-locality form

Resinous botryoidal masses and waxy to resinous replacements of vivianite.

Comment

X-ray amorphous; Partial replacements said to contain poorly crystalline vivianite, but the analogy to the phosphate analog of parasymplesite are unsupported by data.

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen1615.999255.984
51.34%
26FeIronIron355.845167.535
33.60%
15PPhosphorusPhosphorus230.97461.948
12.43%
1HHydrogenHydrogen131.00813.104
2.63%
Total498.571100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Bosphorite
  • IMA2000-052
  • Oxykerchenite
  • Santabarbaraiet

In other languages

German
IMA 2000-052 · Santabarbarait
Spanish
Santabarbaraíta
Italian
Santabarbaraite
Russian
Азовскит

Classification

Strunz
10th ed.

8.CE.80

  • 8Phosphates, Arsenates, VanadatesClass
  • 8.CPhosphates without additional anions, with H2ODivision
  • 8.CEWith only medium-sized cations, RO4:H2O about 1:2.5Group
  • 8.CE.80SantabarbaraiteSpecies

Literature, links & citation

Citations
  1. 2003Jambor, John L., Roberts, Andrew C. (2003) New mineral names. American Mineralogist, 88. 1836-1840
  2. 2003Pratesi, G., Cipriani, C., Giuli, G., Birch, W. (2003) Santabarbaraite: a new amorphous phosphate mineral. European Journal of Mineralogy: 15: 185-192.
  3. 2004Mandarino, Joseph A. (2004) New minerals. The Canadian Mineralogist, 42 (3) 921-945 doi:10.2113/gscanmin.42.3.921 DOI: 10.2113/gscanmin.42.3.921
  4. 2016Frost, Ray L., Scholz, Ricardo, Ruan, Xiuxiu, Lima, Rosa Malena Fernandes (2016) A thermogravimetric, scanning electron microscope and vibrational spectroscopic study of the phosphate mineral santabarbaraite from Santa Barbara mine, Tuscany, Italy. Journal of Thermal Analysis and Calorimetry, 124 (2) 639-644 doi:10.1007/s10973-015-5183-yDOI: 10.1007/s10973-015-5183-y
  5. 2021(2021) Santabarbaraite. Handbook of Mineralogy. Mineralogical Society of America
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Santabarbaraite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/santabarbaraite-11436},
  note      = {Accessed 2026-05-11}
}