Sherwoodite

Ca4.5AlV4+2V5+12O40 · 28H2O
IMA status
  • Approved
  • Grandfathered
IMA symbol
Swd
Discovered
1958
Also known as
  • Sherwoodiet

Where it forms, where it's found

Geological setting

Oxidation of vanadium minerals on fracture surfaces in sandstones and mineralized coalified wood.

sandstone uranium deposits

Type locality
Peanut Mine
  1. Bull Canyon
  2. Montrose County
  3. Colorado
  4. USA

38.2120°, -108.7661°

23recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Translucent
Colour
Dark bluish black (fresh) · blue-green · yellow-green (altered)
Streak
Pale blue.
Fracture
Irregular/Uneven · Sub-Conchoidal
Density
2.8 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.735 – 1.765
Surface relief
High
Principal indices
nω 1.765 · nε 1.735 – 1.738
Pleochroism
Visible

O = green to yellow-brown; E = blue to deep blue-green.

Michel-Lévy diagramhighlighted lineδ = 0.0285
Attainable Michel-Lévy rangeΔ ∈ [0, t·δmax]285 nm1st order
Δ = 0Δmax
Thin-section mosaic70 grains · random 3D orientations
PPLpleochroism per grain
XPLindependent extinctions · rotate the stage
Interference simulatorsingle grain · PPL ↔ XPL
PPLpleochroism only · colour blends on rotation
XPLinterference colour · extinct every 90°
Retardation285 nm
Order1st order
XPL colour

Crystallography

Crystal system
Tetragonal
Space group
I41/amd
Cell parameters
a = 27.9085(7) Å · c = 13.8090(5) Å
Z
4
Morphology

Crystals are equant or slightly flattened. Type material crystals display only two forms: m(110) and d(011).

Type-locality form

Equant or slightly flattened crystals, occurring singly and as polycrystalline aggregates.

Comment

crystallizes as a structural variation of the putative (AlV4+,5+14O40)n− vanadoaluminate complex

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen6815.9991087.932
52.69%
23VVanadiumVanadium1450.942713.188
34.54%
20CaCalciumCalcium4.540.078180.351
8.73%
1HHydrogenHydrogen561.00856.448
2.73%
13AlAluminiumAluminium126.98226.982
1.31%
Total2064.901100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • Sherwoodiet

In other languages

German
Sherwoodit
Italian
Sherwoodite

Classification

Strunz
10th ed.

4.HC.15

  • 4OxidesClass
  • 4.HV[5,6] VanadatesDivision
  • 4.HC[6]-SorovanadatesGroup
  • 4.HC.15SherwooditeSpecies
Dana
8th ed.

47.02.04.01

  • 47Vanadium OxysaltsClass
  • 47.02Anhydrous Vanadium Oxysalts Containing Hydroxyl or HalogenType
  • 47.02.04— unnamed intermediate level —Group
  • 47.02.04.01SherwooditeSpecies
CIM

21.2.9

  • 21Vanadates (and vanadates with arsenate or phosphate)Class
  • 21.2Vanadates of Mg, Ca, Sr or BaGroup
  • 21.2.9SherwooditeSpecies

Literature, links & citation

Citations
  1. 1958Thompson, Mary E., Roach, Carl H., Meyrowitz, Robert (1958) Sherwoodite, a mixed vanadium(IV)-vanadium (V) mineral from the Colorado Plateau. American Mineralogist, 43 (7-8) 749-755
  2. 1978Evans, Howard T. Jr., Konnert, Judith A. (1978) The crystal chemistry of sherwoodite, a calcium 14-vanadoaluminate heteropoly complex. American Mineralogist, 63 (9-10) 863-868
  3. 2005(2005) Sherwoodite. Handbook of Mineralogy. Mineralogical Society of America
  4. 2023Hughes, John M., Kampf, Anthony R., Nash, Barbara P., Marty, Joe (2023) The Atomic Arrangement of the Sherwoodite Structural Unit: Redefinition of the Sherwoodite Vanadoaluminate Heteropoly Complex as [AlV4+V5+12O39]11−. The Canadian Journal of Mineralogy and Petrology, 61 (5). 979-986 doi:10.3749/2300002DOI: 10.3749/2300002
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Sherwoodite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/sherwoodite-3637},
  note      = {Accessed 2026-05-11}
}