Shigaite

Mn6Al3(OH)18[Na(H2O)6](SO4)2 · 6H2O
IMA status
  • Approved
IMA symbol
Sga
Discovered
1985
Also known as
  • IMA1984-057
  • Shigaiet

Where it forms, where it's found

Geological setting

A secondary phase in veins cutting altered manganosite-rhodochrosite-sonolite ore.

Type locality
Ioi mine
  1. Kusatsu City
  2. Shiga Prefecture
  3. Japan

34.9885°, 135.9789°

12recorded occurrences
Source · OpenStreetMap

Physical

Hardness
123456789102/ 10 MOHS
  1. 1Talc
  2. 2Gypsum
  3. 3Calcite
  4. 4Fluorite
  5. 5Apatite
  6. 6Orthoclase
  7. 7Quartz
  8. 8Topaz
  9. 9Corundum
  10. 10Diamond
Transparency
Transparent
Colour
Pale yellow · bright yellow · golden yellow · burnt orange · brown to black if altered · deep yellow with black · inhomogenous inclusions
Streak
Very pale yellow to white
Tenacity
flexible
Cleavage
Perfect

On (0001)

Density
2.32 g/cm³

Optical

Optical type
Uniaxial (-)
Refractive index
1.546
Surface relief
Moderate
Principal indices
nω 1.546
Pleochroism
Visible

O = yellow; E = very pale yellow

UV response
Not fluorescent
Notes

Absorption: O > E ε not determined

Crystallography

Crystal system
Trigonal
Space group
#80
Cell parameters
a = 9.51 Å · c = 32.83 Å
Twinning

On (0001)

Type-locality form

Millimeter-sized tabular hexagonal crystals.

Crystal structure

Chemical composition

Constituent elements
Mass composition breakdown
ElementAtoms At. mass g/mol Mass g/molMass share
8OOxygenOxygen3815.999607.962
52.96%
25MnManganeseManganese654.938329.628
28.71%
13AlAluminiumAluminium326.98280.946
7.05%
16SSulfurSulfur232.06064.120
5.59%
1HHydrogenHydrogen421.00842.336
3.69%
11NaSodiumSodium122.99022.990
2.00%
Total1147.982100.00%

Mass share = atoms × atomic mass ÷ molar mass × 100

From IMA formula

Synonyms

  • IMA1984-057
  • Shigaiet

In other languages

French
shigaite
German
IMA 1984-057 · Shigait
Spanish
shigaíta
Italian
shigaite
Japanese
滋賀石

Classification

Strunz
10th ed.

7.DD.35

  • 7SulfatesClass
  • 7.DSulfates (selenates, etc.) with additional anions, with H2ODivision
  • 7.DDWith only medium-sized cations; sheets of edge-sharing octahedraGroup
  • 7.DD.35ShigaiteSpecies
Dana
8th ed.

31.01.02.01

  • 31Hydrated Sulfates Containing Hydroxyl or HalogenClass
  • 31.01(AB)m(XO4)pZq·xH2O, where m:p > 6:1Type
  • 31.01.02— unnamed intermediate level —Group
  • 31.01.02.01ShigaiteSpecies
CIM

25.9.8

  • 25SulphatesClass
  • 25.9Sulphates of MnGroup
  • 25.9.8ShigaiteSpecies

Group, growth & confusion

Commonly confused with
1 mineral

Literature, links & citation

Citations
  1. 1986Hawthorne, F.C., Bladh, K.W., Burke, E.A.J., Ercit, S., Grew, E.S., Grice, J.D., Puziewicz, J., Roberts, A.C., Schedler, R.A., Shigley, J.E. (1986) New mineral names. American Mineralogist: 71: 1543-1548.
  2. 1987Peacor, D.R., Dunn, P.J., Simmons, W.B., Ramik, R.A. (1987) Ferristrunzite, a new member of the strunzite group, from Blaton, Belgium. Neues Jahrbuch für Mineralogie, Monatshefte 1987, Heft 10, 453-457.
  3. 1992Pring, A., Slade, P. G., Birch, W. D. (1992) Shigaite from Iron Monarch, South Australia. Mineralogical Magazine, 56 (384) 417-419 doi:10.1180/minmag.1992.056.384.15 DOI: 10.1180/minmag.1992.056.384.15
  4. 1996Jambor, J.L., Kovalenker, V.A., Puziewics, J., Roberts, A.C. (1996) New mineral names. American Mineralogist: 81: 1282-1286.
  5. 1996Cooper, Mark A., Hawthorne, Frank C. (1996) The crystal structure of shigaite, [AlMn2+2(OH)6]3(SO4)2Na(H2O)6(H2O)6, a hydrotalcite group mineral. The Canadian Mineralogist, 34 (1) 91-97
Cite this entry
@misc{mineral2026,
  author    = {Mineral Index editorial board},
  title     = {Shigaite — Mineral Index},
  year      = {2026},
  url       = {https://mineralindex.org/minerals/shigaite-3638},
  note      = {Accessed 2026-05-11}
}